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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Description of key information

Hexafluorosilicic acid is listed in Table 3 of Annex VI to the CLP Regulation. (in force from 1 March 2018) as "Skin Corr. 1B (H314). No additional data are available and none are required.

Key value for chemical safety assessment

Skin irritation / corrosion

Endpoint conclusion
Endpoint conclusion:
adverse effect observed (corrosive)

Eye irritation

Endpoint conclusion
Endpoint conclusion:
adverse effect observed (irritating)

Respiratory irritation

Endpoint conclusion
Endpoint conclusion:
no study available

Additional information

Hexafluorosilicic acid is a strong acid that can corrode glass and stoneware (NTP: Haneke & Carson, 2001). Further testing for skin and irritation/damage was waived based on GLP Regulation Annex VII, column 2 specific rules of adaptation of 18 December 2006.

Supporting information from a non-standard histological investigation in the skin of rats, guinea-pigs and pigs also indicate a corrosive effect which may be delayed and is more marked in damaged skin (Alhassan & Zink, 1982). Human experience additionally indicates that the substance is likely to be corrosive.

Justification for classification or non-classification

Hexafluorosilicic acid is a strong acid which is classified as H314 (Causes severe skin burns and eye damage) according CLP Regulation (No. 1272/2008 of 16 December 2008).