Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. Get medical attention immediately. Call a physician.

Skin contact

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing

and shoes. Get medical attention immediately. Take off immediately all contaminated clothing. Wash clothing separately

before reuse.

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. If the affected person is not breathing, apply artificial respiration. Do

not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask

equipped with a one-way valve or other proper respiratory medical device. Call a physician or Poison Control Center

immediately.

Ingestion

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, rinse mouth with water (only if the

person is conscious). Never give anything by mouth to a victim who is unconscious or is having convulsions. If swallowed, do

NOT induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.

Notes to physician

Keep victim under observation. Symptoms may be delayed. Provide general supportive measures and treat symptomatically.

Fire-fighting measures

Flammable properties

Heat may cause the containers to explode. Vapors may travel considerable distance to a source of

ignition and flash back. Runoff to sewer may cause fire or explosion hazard.

Extinguishing media

Suitable extinguishing media

Water Fog. Foam. Carbon dioxide (CO2). Dry chemical, CO2, water spray or alcohol resistant foam. Powder.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Protection of firefighters

Specific hazards arising from the chemical

May form explosive peroxides. Fire may produce irritating, corrosive and/or toxic gases. May include oxides of nitrogen.

Protective equipment and precautions for firefighters

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber

boots, and in enclosed spaces, SCBA. Structural firefighters protective clothing will only provide limited protection. Cool

containers / tanks with water spray.

Water runoff can cause environmental damage. Dike and collect water used to fight fire.

Fire fighting equipment/instructions

In case of fire and/or explosion do not breathe fumes. Wear full protective clothing, including helmet, self-contained positive

pressure or pressure demand breathing apparatus, and face mask. Move containers from fire area if you can do it without risk.

Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For massive fire

in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Stay upwind.

Specific methods

In the event of fire and/or explosion do not breathe fumes. ALWAYS stay away from tanks engulfed in flame.

Accidental release measures

Personal precautions

Keep unnecessary personnel away. Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and

upwind of spill/leak. Keep out of low areas. Ventilate closed spaces before entering them.

Environmental precautions

Avoid release to the environment. Refer to special instructions/safety data sheets. Prevent further leakage or spillage if safe to do

so. Do not flush into surface water or sanitary sewer system. Prevent entry into waterways, sewers, basements or confined areas.

Methods for containment

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop the flow of material, if this is without

risk. Use water spray to reduce vapors or divert vapor cloud drift.

Methods for cleaning up

Extinguish all flames in the vicinity. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic

sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a

container for later disposal. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills in original containers for re-use. For waste disposal, see section 13 of the MSDS. Soak up with inert absorbent

material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Other information

Clean up in accordance with all applicable regulations.

Handling and storage

Handling

Use only in area provided with appropriate exhaust ventilation. Do not smoke. Do not cut, weld, solder, drill, grind, or expose

containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded.

Do not get this material in contact with skin or eyes. Do not breathe vapors or spray mist. Wear personal protective equipment.

Avoid prolonged exposure. Wash thoroughly after handling. Remove and wash contaminated clothing before re-use.

Storage

Use care in handling/storage. Keep tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, and flame.

The pressure in sealed containers can increase under the influence of heat. This material can accumulate static charge which

may cause spark and become an ignition source. Prevent electrostatic charge build-up by using common bonding and grounding

techniques. Keep in an area equipped with sprinklers. Keep away from food, drink and animal feedingstuffs. Keep out of the reach

of children.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 2924
Shipping information
Proper shipping name and description:
Flammable liquid, corrosive, n.o.s. (TETRAHYDROFURAN, TETRAHYDROFURAN CO-MONOMER)
Language:
English
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2924
Shipping information
Proper shipping name and description:
Flammable liquid, corrosive, n.o.s. (TETRAHYDROFURAN, TETRAHYDROFURAN CO-MONOMER)
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
2924
Shipping information
Proper shipping name and description:
Flammable liquid, corrosive, n.o.s. (TETRAHYDROFURAN, TETRAHYDROFURAN CO-MONOMER)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering controls

Ensure adequate ventilation, especially in confined areas. Use process enclosures, local exhaust ventilation, or other engineering

controls to control airborne levels.

Personal protective equipment

Eye / face protection

Wear safety glasses with side shields (or goggles) and a face shield. Do not get in eyes. Eye wash fountain is recommended.

Skin protection

Avoid contact with the skin. Wear impervious protective clothing to prevent contact with this product. Remove and wash

contaminated clothing before re-use. The use of neoprene gloves is recommended.

Respiratory protection

When workers are facing concentrations above the exposure limit, they must use appropriate certified respirators.

General hygiene considerations

When using, do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Keep away

from food and drink. Handle in accordance with good industrial hygiene and safety practice.

Stability and reactivity

Chemical stability

Risk of ignition. Stable under recommended storage conditions.

Conditions to avoid

Heat, flames and sparks. Avoid temperatures exceeding the flash point.

Hazardous decomposition products

Irritants. Nitrogen oxides (NOx). May form explosive peroxides. Decomposes on heating.

Possibility of hazardous reactions

Polymerization can occur in presence of cationic initiators such as selected Lewis acids or strong proton acids.

Disposal considerations

Disposal instructions

Consult authorities before disposal. Incinerate the material under controlled conditions in an approved incinerator. Do not incinerate sealed containers. Do not allow this material to drain into sewers/water supplies.  Dispose in accordance with all applicable regulations.  Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling or disposal.