Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 234-365-4 | CAS number: 11121-16-7
Guidance on Safe Use
Administrative data
First-aid measures
· General information:
Immediately remove any clothing soiled by the product.
Take note of the following instructions.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in the recovery position for transportation.
· After skin contact:
Remove contaminated clothing immediately.
Immediately wash with water and soap and rinse thoroughly.
If skin irritation occurs, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Do not induce vomiting; call for medical help immediately.
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
Toxic metal oxide smoke
Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear personal protective equipment.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Air turbulences of product dust particles will cause an explosive atmosphere.
Prevent formation of dust.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation.
Air turbulences of product dust particles will cause an explosive atmosphere.
Prevent formation of dust.
Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Damp down dust with water spray.
Keep contaminated washing water and dispose of appropriately.
Methods and material for containment and cleaning up:
Sweep the spill area; avoid raising dust.
Ensure adequate ventilation.
Handling and storage
Precautions for safe handling
Prevent static electric sparks.
Open and handle receptacle with care.
Prevent formation of dust.
Ensure good ventilation/exhaustion at the workplace.
Extractor required at the object.
Use appropriate industrial vacuum cleaners or central vacuum systems for dust removal.
· Information about fire - and explosion protection:
Earth container to avoid electric sparks, especially in contact with flammable substances.
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility:
Do not store together with toxic or very toxic substances, which are combustible.
Store away from foodstuffs.
· Further information about storage conditions:
Store under lock and key and with access restricted to technical experts or their assistants only.
Transport information
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Marine transport (UN RTDG/IMDG)
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Air transport (UN RTDG/ICAO/IATA)
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Special provisions / remarks
- Remarks:
- Transport in bulk according to Annex II
of MARPOL73/78 and the IBC Code
Not applicable.
(
Additional transport information
Additional information
- Special provisions / remarks / other:
- GRACE recommendation for air transport: Cargo
aircraft only.
Not dangerous according to the above
specifications if transported in a packaging of less
or equal than 3 cubic meters.
Exposure controls / personal protection
Additional information about design of technical facilities: No further data; see item Handling and storage
Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Recommended filter device for short term use: Filter P3
· Protection of hands:
Protective gloves.
Wear gloves for protection against mechanical hazards according to EN 388.
Use gloves of stable material (e.g. Nitrile) - if necessary tricoted to improve the wearability.
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves
EN 388: Minimum requirements for efficiency level 1 for all groups.
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer.
Butyl rubber, BR
Nitrile rubber, NBR
Recommended thickness of the material: ³ 0.35 mm
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
· Not suitable are gloves made of the following materials: Strong material gloves
· Eye protection:
Safety glasses.
· Body protection: Protective work clothing.
Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes
may be developed.
Toxic fumes may be released if heated above the decomposition point.
Incompatible materials:
Protect from contamination.
Hazardous decomposition products:
Toxic metal oxide smoke
Disposal considerations
· Disposal methods
· Precautions for disposal:
· Waste treatment methods
· Recommendation: Disposal must be made according to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC
waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste
producer.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
