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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General information: If health disorder happens, call for medical help immediately. Immediately remove any clothing soiled by the product.

After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation.

After skin contact: Immediately wash with water and soap and rinse thoroughly.

After eye contact: Rinse opened eye for several minutes under running water.

After swallowing: Do not induce vomiting; call for medical help immediately.

Fire-fighting measures

Extinguishing media

Suitable extinguishing agents: CO2, alcohol resistant foam, powder, water spray.

For safety reasons unsuitable extinguishing agents: Water with full jet

Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide (CO) Carbon dioxide (CO2) Smoke and soot

Do not use water with full jet to prevend fire spreading.

Advice for firefighters

Protective equipment: Wear self-contained respiratory protective device.

Additional information Cool endangered receptacles with water spray. Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Follow safety measures in chapter "Handling and Storage" and "Exposure contros/personal protection".

Wear protective equipment. Keep unprotected persons away.

Environmental precautions:

Do not allow to penetrate the ground/soil. Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water.

Methods and material for containment and cleaning up:

Wipe up little amounts with absorbent material like cloth or pulp. Water and cleansing agent Absorb with incombustible liquid-binding material (sand, diatomite, universal binders). Dispose of contaminated material as waste according to "Disposal considerations".

Ensure adequate ventilation. Keep ignition source away, do not smoke and avoid flames.

Handling and storage

Precautions for safe handling

personal protection equipment see point "Exposure controls/personal protection".

Ensure good ventilation/exhaustion at the workplace.

Prevent formation of aerosols.

Information about fire - and explosion protection:

Fumes can combine with air to form an explosive mixture.

Moistened solids (e.g. cloth, pulp, filter panel, binder) has to be stored hermetically sealed and/or watered and proper disposed.

Keep ignition sources away - Do not smoke.

Protect against electrostatic charges.

Conditions for safe storage, including any incompatibilities

Storage:

Requirements to be met by storerooms and receptacles:

Store only in unopened original receptacles.

Provide solvent resistant, sealed floor.

Information about storage in one common storage facility:

Store away from oxidising agents.

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well sealed receptacles.

Storage class: 3

Classification according to Betriebssicherheitsverordnung (BetrSichV) Flammable liquid

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
1169
1993
2319
Shipping information
Proper shipping name and description:
UN1169 - Extracts, Aromatic, Liquid
UN1993 - Flammable Liquid, N.O.S. (Terpene hydrocarbons, mixture)
UN2319 - Terpene Hydrocarbons, N.O.S.
Labels:
3
Symbol fish and tree
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
1169
1993
2319
Shipping information
Proper shipping name and description:
UN1169 - Extracts, Aromatic, Liquid
UN1993 - FLAMMABLE LIQUID, N.O.S. (d-limonene), ENVIRONMENTALLY HAZARDOUS
UN2319 - Terpene Hydrocarbons, N.O.S.
Labels:
3
Symbol fish and tree
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
1993
Shipping information
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (d-limonene, alpha-PINENE), MARINE POLLUTANT
Labels:
3
Symbol fish and tree
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
1169
1993
2319
Shipping information
Proper shipping name and description:
UN1169 - Extracts, Aromatic, Liquid
UN1993 - FLAMMABLE LIQUID, N.O.S. (d-limonene)
UN2319 - Terpene Hydrocarbons, N.O.S.
Labels:
3
Remarksopen allclose all

Additional transport information

Additional information
Special provisions / remarks / other:
Product contains environmentally hazardous substances: d-limonene

Exposure controls / personal protection

Personal protective equipment:

General protective and hygienic measures:

Use personal protective equipment depending on concentration and amount of hazardous substance.

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work.

Avoid contact with the skin.

Avoid contact with the eyes and skin.

Respiratory protection:

Suitable respiratory protection:

filter class A2 (brown colour).

Use the rules for application of respiratory protection systems.

In case of brief exposure or low pollution use respiratory filter device.

In case of intensive or longer exposure use self-contained respiratory protective device.

Protection of hands:

Preventive skin protection by use of skin-protecting agents is recommended.

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

Material of gloves:

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Penetration time of glove material > 480 minutes at layerthickness of 0,425 millimeter (Sol-Vex 37-695/Ansell).

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

For the permanent contact gloves made of the following materials are suitable: Nitrile rubber, NBR

E.g. following product: Sol-Vex (37-695) from Ansell.

As protection from splashes gloves made of the following materials are suitable:Nitrile rubber, NBR

Eye protection: Tightly sealed goggles according to EN 166:2001

Body protection: Protective work clothing

Stability and reactivity

Thermal decomposition / conditions to be avoided: Heating causes vaporisation and formation of ignitable atmosphere is possible.

Materials to be avoided:

Dangerous reactions: Formation of explosive gas mixture with air possible. In case of unpropitious storing conditions (air admission, heat accumulation) selfignition is possible for moistened solids (e.g. cloth, pulp, filter panel, binder). Reacts violently with oxidizing agents.

Dangerous decomposition products: No dangerous decomposition products expected by intended use.

Disposal considerations

Product:

Recommendation: Recycling is prefered to disposal or burning. Disposal must be made according to official regulations. Must not be disposed together with household garbage. Do not allow product to reach sewage system. European waste catalogue: e.g. 02 03 03 wastes from solvent extraction.

Uncleaned packaging:

Recommendation: Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning. Packagings that may not be cleansed are disposed of in the same manner as the product.

Contaminated solids:

Recommendation: Moistende solids (e.g. cloth, pulp, filter panels, binder) can be burnt after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. European waste catalogue: e.g. 15 02 02 Filter and absorption materials contaminated with hazardous agents.