Registration Dossier
Registration Dossier
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EC number: 230-625-6 | CAS number: 7226-23-5
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms
are possible
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
5.2. Special hazards arising from the substance or mixture
carbon monoxide, Carbon dioxide, toxic gases/vapours, nitrous gases
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible.
7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place. Protect against moisture.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
PNEC
freshwater: 0.10279 mg/l
marine water: 0.010279 mg/l
intermittent release: 1.0279 mg/l
STP: 10 mg/l
sediment (freshwater): 0.46 mg/kg
sediment (marine water): 0.046 mg/kg
soil: 0.0316 mg/kg
oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.
DNEL
worker:
Long-term exposure- systemic effects, Inhalation: 0.411 mg/m3
worker:
Long-term exposure- systemic effects, dermal: 0.233 mg/kg
consumer:
Long-term exposure- systemic effects, Inhalation: 0.072 mg/m3
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is required additionally to the stated personal protection equipment. The substance was registered as a transported isolated intermediate. The manufacturer/importer has received the confirmation by the user that the substance is used under strictly controlled conditions in accordance with
Art. 18 of the REACH regulation (EC) No 1907/2006. Take off immediately all contaminated clothing. Store work clothing separately.
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Formation of flammable gases:
Remarks: Forms no flammable gases in the presence of water.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
Reacts with oxidizing agents.
10.4. Conditions to avoid
Avoid extreme temperatures. Avoid humidity.
10.5. Incompatible materials
Substances to avoid:
oxidizing agents
10.6. Hazardous decomposition products
Thermal decomposition products:
carbon oxides, nitrogen oxides
Disposal considerations
13.1. Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/
authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
