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Physical & Chemical properties

Vapour pressure

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Administrative data

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2015
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: peer reviewed
Qualifier:
according to guideline
Guideline:
other: ASTM method E1719
Principles of method if other than guideline:
Standard Test Method for Vapor Pressure of Liquids by Ebulliometry
GLP compliance:
not specified
Type of method:
other: Standard Test Method for Vapor Pressure of Liquids by Ebulliometry
Test no.:
#1
Temp.:
ca. 104 °C
Vapour pressure:
ca. 760 mm Hg
Remarks on result:
other: Boiling Point
Test no.:
#2
Temp.:
ca. 25 °C
Vapour pressure:
ca. 21.13 mm Hg

The measured vapor pressure data was correlated to the Antoine equation using the Thermal ANTOINE program using Thomson’s rule to constrain the C value.Using the Antoine parameters, the normal boiling point (VP at 760 mmHg) of the sample is 104.0 °C, and the vapor pressure at 25 ° is 21.13 mmHg.

Conclusions:
Using the Antoine parameters, the normal boiling point (VP at 760 mmHg) of the sample is 104.0 °C, and the vapor pressure at 25 ° is 21.13 mmHg.

Description of key information

No experimental data is available for disodium dihydrogen ethylenediaminetetraacetate. Read across to editic acid was done instead.

The vapour pressure of edetic acid was determined to be 2E-012 hPa at 25°C according to Riedel and Plank.

The measured vapor pressure data was correlated to the Antoine equation using the Thermal ANTOINE program using Thomson’s rule to constrain the C value.Using the Antoine parameters, the normal boiling point (VP at 760 mmHg) of the sample is 104.0 °C, and the vapor pressure at 25 ° is 21.13 mmHg.

Key value for chemical safety assessment

Additional information

The vapour pressure determined for the acid form of EDTA represents also a worst case (highest) value for its sodium salts as it is belived that only the free acid can evaporate. In conclusion the value extrapolated for the free acid will also be used for the exposure calculations of the sodium salts in the chemical safety report, reflecting a worst case assumption.