Registration Dossier
Registration Dossier
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EC number: 214-011-5 | CAS number: 1072-62-4
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Fire-fighting measures
Extinguishing media
- suitable extinguishing media: water spray, dry powder, foam, carbon dioxide.
- unsuitable extinguishing media for safety reasons: water jet.
Additional information: avoid whirling up the material/product because of the danger of dust explosion.
Special hazards arising from the substance or mixture: hydrogen cyanide, nitrous gases can be released in case of fire. Dust explosion hazard.
Advice for fire-fighters
Special protective equipment: wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
- collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
- dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
- suitable extinguishing media: water spray, dry powder, foam, carbon dioxide.
- unsuitable extinguishing media for safety reasons: water jet.
Additional information: avoid whirling up the material/product because of the danger of dust explosion.
Special hazards arising from the substance or mixture: hydrogen cyanide, nitrous gases can be released in case of fire. Dust explosion hazard.
Advice for fire-fighters
Special protective equipment: wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
- collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
- dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation. Do not breathe dust.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
- for small amounts: Pick up with suitable appliance and dispose of.
- for large amounts: Pick up with suitable appliance and dispose of.
Collect waste in suitable containers, which can be labeled and sealed. Avoid raising dust. Use sparkproof tools and explosion-proof equipment. Dispose of absorbed material in accordance with regulations.
Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation. Do not breathe dust.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
- for small amounts: Pick up with suitable appliance and dispose of.
- for large amounts: Pick up with suitable appliance and dispose of.
Collect waste in suitable containers, which can be labeled and sealed. Avoid raising dust. Use sparkproof tools and explosion-proof equipment. Dispose of absorbed material in accordance with regulations.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Wear suitable protective clothing and eye/face protection.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Avoid dust formation. The product is capable of dust explosion.
Conditions for safe storage, including any incompatibilities
- segregate from acids and acid forming substances.
- keep container tightly closed in a cool, well-ventilated place.
Storage stability:
- Storage temperature: 20 °C
- Storage duration: 24 months
Ensure thorough ventilation of stores and work areas. Wear suitable protective clothing and eye/face protection.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Avoid dust formation. The product is capable of dust explosion.
Conditions for safe storage, including any incompatibilities
- segregate from acids and acid forming substances.
- keep container tightly closed in a cool, well-ventilated place.
Storage stability:
- Storage temperature: 20 °C
- Storage duration: 24 months
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Personal protective equipment
Respiratory protection:
Breathing protection if dusts are formed. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): butyl rubber (butyl) - 0.7 mm coating thickness fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN 374) chloroprene rubber (CR) - 0.5 mm coating thickness polyvinylchloride (PVC) - 0.7 mm coating thickness nitrile rubber (NBR) - 0.4 mm coating thickness
natural rubber/natural latex (NR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene
Respiratory protection:
Breathing protection if dusts are formed. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): butyl rubber (butyl) - 0.7 mm coating thickness fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN 374) chloroprene rubber (CR) - 0.5 mm coating thickness polyvinylchloride (PVC) - 0.7 mm coating thickness nitrile rubber (NBR) - 0.4 mm coating thickness
natural rubber/natural latex (NR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
Reacts with strong acids. Exothermic reaction. Dust explosion hazard.
10.4. Conditions to avoid
See MSDS section 7 - Handling and storage.
10.5. Incompatible materials
Substances to avoid:
strong acids
10.6. Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
Reacts with strong acids. Exothermic reaction. Dust explosion hazard.
10.4. Conditions to avoid
See MSDS section 7 - Handling and storage.
10.5. Incompatible materials
Substances to avoid:
strong acids
10.6. Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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