Registration Dossier
Registration Dossier
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EC number: 212-094-2 | CAS number: 762-16-3
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice
:
Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
If inhaled
:
Remove to fresh air.
Rinse nose and mouth with water.
In case of skin contact
:
Take off contaminated clothing and shoes immediately.
Wash the skin immediately with soap and water.
If skin irritation persists, call a physician.
In case of eye contact
:
Rinse with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
:
Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person.
Obtain medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
:
The symptoms and effects are as expected from the hazards
as shown in section 2. No specific product related symptoms are known.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
:
Treat symptomatically.
Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
:
High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during firefighting / Specific hazards arising from the chemical
:
CAUTION: reignition may occur.
Supports combustion.
Do not use a solid water stream as it may scatter and spread fire.
Water spray may be ineffective unless used by experienced firefighters.
Heating may cause decomposition with release of toxic fumes.
Risks of ignition followed by flame propagation or secondary explosions shall be prevented by avoiding accumulation of dust, e.g. on floors and ledges.
Combustion products
:
Fire will produce smoke containing hazardous combustion products (see section 10).
5.3 Advice for firefighters
Special protective equipment for firefighters
:
In the event of fire, wear self-contained breathing apparatus.
Further information
:
Use water spray to cool unopened containers.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
:
Use personal protective equipment.
Wear respiratory protection.
Avoid dust formation.
Avoid breathing dust.
Ensure adequate ventilation.
Remove all sources of ignition.
6.2 Environmental precautions
Environmental precautions
:
Prevent product from entering drains.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up /
:
Keep wetted with water.
Methods for containment
Soak up with inert absorbent material and dispose of as hazardous waste.
Confinement must be avoided.
Pick up and arrange disposal without creating dust.
Keep in suitable, closed containers for disposal.
Never return spills in original containers for re-use.
6.4 Reference to other sections
Additional advice
:
For personal protection see section 8.
Handling and storage
7.1 Precautions for safe handling
Advice on safe handling
:
For personal protection see section 8.
Avoid formation of respirable particles.
Do not breathe vapours/dust.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.
Smoking, eating and drinking should be prohibited in the application area.
Open drum carefully as content may be under pressure.
Avoid contact with skin, eyes and clothing.
Advice on protection against fire and explosion
:
Use explosion protected equipment.
Provide appropriate exhaust ventilation at places where dust is formed.
Keep away from sources of ignition - No smoking.
No sparking tools should be used.
Keep away from reducing agents (e.g. amines), acids, alkalies and heavy metal compounds (e.g. accelerators, driers, metal soaps).
Do not cut or weld on or near this container even when empty.
Keep away from combustible material.
Temperature class
:
It is recommended to use electrical equipment of temperature group T3. However, autoignition can never be excluded.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
:
No smoking.
Keep in a dry place.
Observe label precautions.
Electrical installations / working materials must comply with the technological safety standards.
Store at room temperature in the original container.
Keep only in original container.
Store away from other materials.
Maximum storage
:
5 °C
temperature:
Other data
:
No decomposition if stored and applied as directed.
7.3 Specific end use(s)
Specific use(s)
:
Consult the technical guidelines for the use of this substance/mixture.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3114
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3114
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3114
Shipping information
- Proper shipping name and description:
- Organic Peroxide Type C, Solid, Temperature Controlled (dioctanoyl peroxide)
- Chemical name:
- dioctanoyl peroxide
- Labels:
- 5.2
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not permitted for transport
Shipping information
- Proper shipping name and description:
- Not permitted for transport
- Chemical name:
- Not permitted for transport
- Labels:
- Not permitted for transport
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Engineering controls
Explosion proof ventilation recommended.
Provide appropriate exhaust ventilation at places where dust is formed.
Personal protective equipment
Respiratory protection
:
Half mask with a particle filter P2 (EN 143)
Hand protection
:
butyl-rubber
Neoprene
Eye protection
:
Tightly fitting safety goggles
Skin and body protection
:
Protective suit
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Wash contaminated clothing before re-use.
Environmental exposure controls
General advice
:
Prevent product from entering drains.
Stability and reactivity
10.1 Reactivity
Stable under normal conditions.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Dust may form explosive mixture in air.
10.4 Conditions to avoid
Conditions to avoid
:
Confinement must be avoided.
Heat, flames and sparks.
10.5 Incompatible materials
Materials to avoid
:
Contact with incompatible materials will result in hazardous decomposition.
For queries regarding the suitability of other materials please contact the supplier.
Do not mix with peroxide accelerators, unless under controlled processing.
Use only stainless steel 316, PP, polyethylene or glass-lined equipment.
Acids and bases
Iron
Copper
Reducing agents
Heavy metals
Rust
10.6 Hazardous decomposition products
Hazardous decomposition products
:
heptane
Carbon oxides
tetradecane
Nonyl decanoate
Thermal decomposition
:
SADT - (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating decomposition may occur with a substance in the packaging as used in transport. A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by thermal decomposition at and above the SADT. Contact with incompatible substances can cause decomposition below the SADT.
Self-Accelerating decomposition temperature (SADT)
:
25 °C
Disposal considerations
13.1 Waste treatment methods
Product
:
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Hazardous waste
Dispose of contents/container in accordance with local regulation.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not burn, or use a cutting torch on, the empty drum.
Due to the high risk of contamination recycling/recovery is not recommended.
Follow all warnings even after the container is emptied.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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