Registration Dossier
Registration Dossier
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EC number: 204-594-4 | CAS number: 123-04-6
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
dry powder, foam, carbon dioxide, water spray
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture
fumes/smoke, chlorine compounds
Under special fire conditions traces of other toxic substances are possible.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems. Dispose of fire debris and contaminated extinguishing water in accordance with official
regulations. If exposed to fire, keep containers cool by spraying with water.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Sources of ignition should be kept well clear. Use personal protective
clothing. Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Contain with absorbent material (e.g. sand, silica gel, acid binder, general
purpose binder, sawdust).
For large amounts: Contain with absorbent material (e.g. sand, silica gel, acid binder, general
purpose binder, sawdust).
Collect waste in suitable containers, which can be labeled and sealed.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Keep away from sources of ignition - No
smoking.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from strong acids. Segregate from strong bases. Segregate from amines. Segregate from
oxidizable substances.
Suitable materials for containers: Stainless steel 1.4541, Stainless steel 1.4571, Isolemail PM Noir,
glass, High density polyethylene (HDPE)
Storage stability:
Storage temperature: < 40 °C
Storage duration: 12 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Components with workplace control parameters
123-04-6: 3-(Chloromethyl)heptane
24468-13-1: 2-Ethylhexyl chloroformate
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Wear respiratory protection if ventilation is
inadequate. Combination filter for gases/vapours of organic, inorganic, acid inorganic and alkaline
compounds (e.g. EN 14387 Type ABEK). Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
polyvinylchloride (PVC) - 0.7 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment. Do not inhale
gases/vapours/aerosols. Avoid contact with skin and eyes. No eating, drinking, smoking or tobacco
use at the place of work. Hands and/or face should be washed before breaks and at the end of the
shift. Wash contaminated clothing before reuse.
Stability and reactivity
Reactivity
Corrosion to metals: Not corrosive to: steel
Formation of
flammable gases:
Remarks: Forms no flammable gases in the
presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Reacts with strong acids. Reacts with alkalies. Reacts with oxidizing agents.
The product is chemically stable.
Conditions to avoid
Avoid humidity. Avoid heat. Avoid prolonged storage.
Incompatible materials
Substances to avoid:
alkaline reactive substances, bases, amines
Hazardous decomposition products
Possible thermal decomposition products:
hydrogen chloride
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Do not reuse empty containers.
Dispose of in accordance with national, state and local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
