Registration Dossier

Administrative data

First-aid measures

General information: Consult physician
After inhalation: Move victim to fresh air. Put victim at rest and keep warm. In case of irritation of the respiratory tract seek medical advice.
After contact with skin: After contact with skin, wash immediately with plenty of Water and soap. In case of skin irritation, seek medical treatment.
After contact with eyes: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Consult anopthalmologist.
After ingestion: Rinse mouth immediately and drink large quantities of water.

Fire-fighting measures

Suitable extinguishing media: Carbon dioxide (CO2). Foam. Extinguishing powder. Water spray. Atomized water.
Extinguishing media which must not be used for safety reasons: High power water jet.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting gases: Formaldehyde. Hydrochloric (HCl). Carbon monoxide. Carbon dioxide (CO2).
Special protective equipment for fire-fighters: In case of fire: Wear self-contained breathing apparatus.
Additional information: Contaminated fire-fighting water must be collected separately. Do not empty into drains or the aquatic environment.

Accidental release measures

Personal precautions: Wear personal protection equipment. Avoid contact with skin and eyes.
Environmental precautions: Do not empty into drains or the aquatic environment.
Methods for cleaning up/taking up: Soak up inert absorbent and dispose as waste requiring special observation. (Sand, Kieselgur.)

Handling and storage

Handling
Advice on safe handling: In case of open handling equipment with built-in suction must be used. It is recommended to organise all working processes in order to exclude the following: skin contact. Eye contact. Working areas must be arranged in such a manner that they can be cleaned at all times.
Advice on protection against fire and explosion: Take precautionary measures against static discharges.
Storage
Requirements for storage rooms and vessels: Keep container tightly closed in a cool, well-ventilated place. Do not empty into drains or the aquatic environment. Further information on storage conditions: Keep away from food, drink and animal feedingstuffs.

Transport information

Land transport (ADR/RID)

UN number:
2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
Reaction mass of Bis(2-chloroethoxy)methane and 1,15-dichloro-3,5,8,11,13-pentaoxa-pentadecane (PrePolymer D)
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
II
Labels:
6.1
Special Provisions:
274 614
Remarks:
Limited quantity: 100 mL
Transport category: 2
Hazard No: 60
Tunnel restriction code: D/E
Other applicable information (land transport):E4

Inland waterway transport (ADN(R))

UN number:
2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
Reaction mass of Bis(2-chloroethoxy)methane and 1,15-dichloro-3,5,8,11,13-pentaoxa-pentadecane (PrePolymer D)
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
II
Labels:
6.1
Remarks
Hazard label: 6.1
Classification code: T1
Special Provisions: 274 614 802
Limited quantity: 100 mL
Other applicable information (inland waterways transport):E4

Marine transport (IMDG)

UN number:
2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
Reaction mass of Bis(2-chloroethoxy)methane and 1,15-dichloro-3,5,8,11,13-pentaoxa-pentadecane (PrePolymer D)
Class:
6.1
Packaging group:
II
EmS code:
F-A, S-A
Labels:
6.1
Remarks
Special Provisions: 274
Limited quantity: 100 mL
Other applicable information (marine transport): E4

Air transport ICAO/IATA

UN number:
2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
Reaction mass of Bis(2-chloroethoxy)methane and 1,15-dichloro-3,5,8,11,13-pentaoxa-pentadecane (PrePolymer D)
Class:
6.1
Packaging group:
II
Labels:
6.1
Remarks
Special Provisions: A3 A4 A137
Limited quantity Passenger: 1 L
IATA-packing instructions- Passenger: 654
IATA-max. quantity - Passenger: 5 L
IATA-packing instructions - Cargo: 662
IATA-max. quantity - Cargo: 60 L
Other applicable information (air transport): E4
Passenger-LQ: Y641
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Occupational exposure controls: Bis(2-chloroethoxy)methane and 1,15-dichloro-3,5,8,11,13-pentaoxa-pentadecane (PrePolymer D): To date, no national limit values exist.
Protective and hygiene measures: Wash hands before breaks and at the end of work. Do not eat, drink, smoke or sneeze at the workplace.
Respiratory protection: Do not breathe gas/fumes/vapour/spray.
Hand protection: Tested protective gloves are to be worn: German Industry Norms (DIN) / European Norms (EN): EN 420 Suitable material: CR (polychloroprenes, Chloroprene rubber)., FKM (Fluoroelastomer (Viton)).
Eye protection: Suitable eye protection: Goggles. German Industry Norms (DIN) / European Norms (EN): EN 166 Face protection shield.
Skin protection: For the protection against direct skin contact, body protective clothing is essential (in addition to the usual working clothes). Apron. Boots. chemical resistant suit. (DIN-EN 465)
Environmental exposure controls: Handling and storage. No further action is necessary.

Safe uses can be guaranteed only for the working conditions as mentioned in chapter 10 of the CSR, in combination with the risk management measures mentioned in the table below.

Process Category Exposure time Risk Management Measures (RMMs) to be used, in order to ensure SAFE USE
2 >4 hours Local Exhaust Ventilation (LEV) (90% efficiency) in combination with gloves 1-4 hours Local Exhaust Ventilation (LEV) (90% efficiency) in combination with gloves <15 minutes No requirements
3 >4 hours Exhaust Ventilation (LEV) (90% efficiency) in combination with a half mask PLUS gloves
>15 – 60 min. Local Exhaust Ventilation (LEV) (90% efficiency) or a half mask
15 <15 minutes Local Exhaust Ventilation (LEV) (90% efficiency)

Stability and reactivity

Conditions to avoid: Decomposition takes place from temperatures above: 140°C
Materials to avoid: Alkalis (alkalis), concentrated. acid, concentrated. Oxidizing agents, strong.
Hazardous decomposition products: Formaldehyde. Hydrochloric (HCl). Carbon monoxide. Carbon dioxide (CO2).

Disposal considerations

Advice on disposal: Waste disposal according to official state regulations. Cleaned containers may be recycled.
Waste disposal number of waste from residues/unused products: 070107

WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals; halogenated still bottoms and reaction residues Classified as hazardous waste.
070107
WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals; halogenated still bottoms and reaction residues Classified as hazardous waste.
Waste disposal number of contaminated packaging:070107
WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals; halogenated still bottoms and reaction residues
Classified as hazardous waste