Registration Dossier

Administrative data

First-aid measures

General advice-
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely.
Inhalation-
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.
Skin contact-
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.
Eye contact-
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.
Ingestion-
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.
Most important symptoms and effects, both acute and delayed Symptoms: No symptoms known or expected.
Indication of any immediate medical attention and special treatment needed Treatment: Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote.

Fire-fighting measures

Extinguishing media-
Suitable: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable: High volume water jet
Special hazards arising from the substance or mixture-
In the event of fire the following may be released:, Hydrogen cyanide (hydrocyanic acid), Hydrogen fluoride, Carbon monoxide (CO), Sulphur oxides, Nitrogen oxides (NOx)
Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.
Advice for firefighters
Special protective equipment for firefighters-
In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.
Further information
Contain the spread of the fire-fighting media. Do not allow run-off from fire-fighting to enter drains or water courses.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Precautions:
Remove all sources of ignition. Avoid dust formation. Keep people away from and upwind of spill/leak. Avoid contact with product or contaminated surfaces. Use personal protective equipment.
Environmental precautions
Do not allow to get into surface water, drains and ground water.
Methods and materials for containment and cleaning up
Methods for cleaning up
Avoid dust formation. Use mechanical handling equipment. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations.

Handling and storage

Precautions for safe handling
Advice on safe handling- Avoid dust formation. Traces of hydrogen cyanide vapour can collect in the empty space of closed containers. Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion-
Dust may form explosive mixture in air. Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.
Hygiene measures-
Avoid contact with skin, eyes and clothing. Keep working clothes
separately. Wash hands before breaks and immediately after handling the product. Wash hands immediately after work, if necessary take a shower. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers-
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight.
Advice on common storage-
Keep away from food, drink and animal feeding stuffs.
Suitable materials-
LDPE (low density polyethylene), Polypropylene-foil (PP)

Transport information

Land transport (ADR/RID)

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
Chemical name:
PYRASULFOTOLE
Language:
English
Class:
9
Classification code:
9
Packaging group:
III
Labels:
No. 9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
Chemical name:
PYRASULFOTOLE
Language:
English
Class:
9
Classification code:
9
Packaging group:
III
Labels:
No. 9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
Chemical name:
PYRASULFOTOLE
Class:
9
Packaging group:
III
Labels:
No. 9
Remarks
Marine pollutant = true

Air transport ICAO/IATA

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
Chemical name:
PYRASULFOTOLE
Class:
9
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Respiratory protection
If product is handled while not enclosed, and if contact may occur:
Wear respirator with a particle filter mask (protection factor 20) conforming to European Norm EN149FFP3 or EN140P3 or equivalent.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.

Hand protection
Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Wash gloves when contaminated. Dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.
Material: Nitrile rubber
Rate of permeability > 480 min
Glove thickness > 0.4 mm
Protective index: Class 6
Directive: Protective gloves complying with EN 374.

Eye protection
Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection
Wear standard coveralls and Category 3 Type 4 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.
If there is a risk of significant exposure, consider a higher protective type suit.
If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.

Stability and reactivity

Reactivity:
Thermal decomposition-
from 245 °C, Heating rate: 3 K/min
Exothermic decomposition.
Chemical stability-
Stable under normal conditions.
Possibility of hazardous reactions-
Incapable of deflagration
No hazardous reactions when stored and handled according to prescribed instructions.
Conditions to avoid-
Extremes of temperature and direct sunlight.
Incompatible materials-
Store only in the original container.
Hazardous decomposition products-
No decomposition products expected under normal conditions of use.

Disposal considerations

Waste treatment methods
Product: In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging:
Not completely emptied packagings should be disposed of as hazardous waste.
Waste key for the unused product:
02 01 08* agrochemical waste containing hazardous substances