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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Hydrolysis

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
hydrolysis
Data waiving:
study technically not feasible
Justification for data waiving:
other:
Reason / purpose for cross-reference:
data waiving: supporting information

Description of key information

Key value for chemical safety assessment

Additional information

A standard hydrolysis study with silane is considered technically unfeasible because the substance is a pyrophoric gas.

In a secondary source to which reliability could not be assigned, silane is attacked by water in the presence of minute traces of hydroxyl ion to evolve hydrogen and form silicic acid/silica or hydrated silicon dioxide. The reaction with water is further accelerated by larger amounts of inorganic or organic bases.

The final products on reaction with water and/or air are expected to be hydrogen, silicic acid (SiO2.nH2O) and/or silica.

In addition, in O'Neil 2013, silane was reported to slowly decomposes in water, and be practically insoluble in alcohol, ether, benzene, chloroform, silicochloroform and silicon tetrachloride, and to decompose in potassium hydroxide solutions.

Reference:

O'Neil M J (2013). The MERCK Index. An encyclopedia of chemicals, drugs, and biologicals. Fifteenth Edition. The Royal Society of Chemistry