Ethyldiisopropylamine

Guidance on Safe Use

First-aid measures

General advice: Under the shower: Take off immediately all contaminated clothing (including shoes).

Inhalation of mists Move patient from contaminated area to fresh air. Oxygen or artificial respiration if needed. Keep under medical

surveillance. In case of problems : Hospitalise.

Skin contact: Wash immediately, abundantly and thoroughly with water. Consult a physician. In case of extensive burns, hospitalize.

Eye contact: Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately.

Ingestion: If swallowed, do not induce vomiting - seek medical advice.

Protection of first-aiders: If entering a saturated atmosphere, wear a self contained breathing apparatus. Protective suit

Fire-fighting measures

Suitable extinguishing media: Water spray, Foam, Dry powder, Carbon dioxide (CO2)

Unsuitable extinguishing media: High volume water jet

Special hazards arising from the substance or mixture:

Flammable. Possible re-ignition of vapours from a distance

Thermal decomposition giving toxic products:, Ammonia, Carbon oxides

Formation of toxic products through combustion:, Nitriles, Cyanides

Advice for firefighters:Specific methods:

Use water spray to cool unopened containers. Ensure containers can be rapidly moved. In case of fire nearby, remove exposed containers.

Prohibit all sources of sparks and ignition - Do not smoke.

Special protective actions for fire-fighters:

In the event of fire, wear self-contained breathing apparatus. Complete suit protecting against chemicals.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Use personal protective equipment. Prohibit contact with skin and eyes and inhalation of vapours. Ensure adequate ventilation. Evacuate

personnel to safe areas. Prohibit all sources of sparks and ignition - Do not smoke. Beware of vapours accumulating to form explosive

concentrations. Vapours can accumulate in low areas.

Environmental precautions:

Prevent product from entering drains. Dam up with sand or inert earth (do not use combustible materials). Should not be released into the

environment.

Methods and materials for containment and cleaning up:

Recovery:

Pump into a labelled inert emergency tank. Moist product : absorb the remainder with an inert absorbent material.

Capture the gas with fine water spray (scrubbing), collect and treat contaminated water.

Neutralisation: Neutralize with a sodium bisulphate solution.

Elimination: Destroy the product by incineration (in accordance with local and national regulations).

Handling and storage

Precautions for safe handling:Technical measures/Precautions:

Storage and handling precautions applicable to products: Liquid. Highly flammable Toxic. Corrosive. With vapours explosive in air. Provide

appropriate exhaust ventilation at machinery. Provide fire-blanket nearby. Provide showers, eye-baths Provide water supplies near the point

of use. Provide electrical earthing of equipment and electrical equipment usable in explosive atmospheres.

Safe handling advice:

Take precautionary measures against static discharges. Open drum carefully as content may be under pressure. Provide waterproof electrical

equipment. Prohibit all sources of sparks and ignition - Do not smoke. Use only in an area containing explosion proof equipment. Do not use

air for transfers. In case of insuffisant ventilation, wear

Hygiene measures:

Prohibit contact with  eyes and inhalation of vapours. Avoid contact with skin. When using do not eat, drink or smoke.

Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.

Conditions for safe storage, including any incompatibilities:

Keep in a dry, cool and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Store protected from moisture and heat. Remove all sources of ignition. Store under inert and dry atmosphere. Provide electrical earthing of

equipment and electrical equipment usable in explosive atmospheres. Provide a catch-tank in a bunded area. Provide impermeable floor.

Do not store above: 50 °C

Packaging material:

Recommended: Ordinary steel

To be avoided: Aluminium and copper alloys., Zinc and alloys, Rubber, Galvanized steel, Plastic materials

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3384

Shipping information

Proper shipping name and description:

TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S.
(ETHYLDIISOPROPYLAMINE), DANGEROUS FOR THE ENVIRONMENT

Chemical name:

(ETHYLDIISOPROPYLAMINE)

Labels:

6.1 +3

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3384

Shipping information

Proper shipping name and description:

TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S.
(ETHYLDIISOPROPYLAMINE), DANGEROUS FOR THE ENVIRONMENT

Chemical name:

(ETHYLDIISOPROPYLAMINE)

Labels:

6.1 +3

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3384

Shipping information

Proper shipping name and description:

TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S.
(ETHYLDIISOPROPYLAMINE)

Chemical name:

(ETHYLDIISOPROPYLAMINE)

Labels:

6.1 + 3

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3384

Shipping information

Proper shipping name and description:

TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S.
(ETHYLDIISOPROPYLAMINE)

Chemical name:

(ETHYLDIISOPROPYLAMINE)

Labels:

6.1 + 3

Remarks

SpecialProvisions

Exposure controls / personal protection

CONTROL PARAMETERS:

Exposure Limit Values Contains no substances with occupational exposure limit values.

EXPOSURE CONTROLS:

General protective measures: Provide sufficient air exchange and/or exhaust in work rooms.

Personal protective equipment:

Respiratory protection: Low concentrations or short activity: Mask with specific cartridge Recommended Filter type: A2B2E2K2P3

High concentrations or prolonged activity: Self contained Breathing Apparatus

Hand protection: Gloves (PVC, neoprene)

According to permeation index EN 374: 1 (time elapsed > 10 mins)

Eye/face protection: Safety glasses with side-shields

Skin and body protection: At the workplace : Protective clothing (cotton)

Intervention at incident: Waterproof suit

Stability and reactivity

Reactivity & Chemical stability: The product is stable under normal handling and storage conditions.

Conditions to avoid:Temperatures above 50 °C Exposure to moisture. Protect from heat.

Incompatible materials to avoid:

• Violent reaction and flammability with :, Oxidizing agents, Nitrates, Peroxides

• Very exothermic reaction and possibility of spitting with :, Strong acids, Halogens, Product likely to react violently in alkaline environment

• Formation of toxic products (n-nitrosamines) with:, Nitrous acid and other nitrosating agents, Nitrites, Oxygen

• Very exothermic reaction with :, Water

Corrosion with : light metals and alloys

Hazardous decomposition products:

Thermal decomposition giving toxic and corrosive products :, Ammonia, Carbon oxides, Nitriles, Cyanides

Disposal considerations

Disposal of product: Neutralize with a sodium bisulphate solution. Destroy the product by incineration (in accordance with

local and national regulations).

Disposal of packaging: Purging of residual gases in empty packaging is obligatory before recovery. Destroy packaging by

incineration at an approved waste disposal site. Clean container with water. Recover waste water for

processing later.