Reaction mass of N,N,N',N'-tetrabutylmethylenediamine and dibutylamine

Guidance on Safe Use

First-aid measures

- General advice:

Get medical attention immediately. Show this Safety Data Sheet to the medical personnel

- Following inhalation:

Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Place unconscious person on their side in the recovery position and ensure breathing can take place.

- Following skin contact:

It is important to remove the substance from the skin immediately. Take off immediately all contaminated clothing. Remove contamination with soap and water or recognised skin cleansing agent. Get medical attention.

- Following eye contact:

Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 10 minutes.

- Following ingestion:

Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Do not induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Place unconscious person on their side in the recovery position and ensure breathing can take place. Maintain an open airway. Loosen tight clothing such as collar, tie or belt.

- Most important symptoms and effects: Inhalation - A single exposure may cause the following adverse effects: Headache. Exhaustion and weakness. Ingestion - May cause sensitisation or allergic reactions in sensitive individuals. May cause discomfort if swallowed. Stomach pain. Nausea, vomiting. May cause muatagenic effects.  Skin contact - May cause skin sensitisation or allergic reactions in sensitive individuals. A single exposure may cause the following adverse effects: Pain. Eye contact - Irratating to eyes. 

- Protection of first aiders - First aid personnel should wear appropriate protective equipment during any rescue. If it is suspected that volatile contaminants are still present around the affected person, first aid personnel should wear an appropriate respirator or self-contained breathing apparatus. Wash contaminated clothing thoroughly with water before removing it from the affected person, or wear gloves. It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation.

- Notes for the doctor - Treat symptomatically. Keep affected person under observation. May cause sensitisation or allergic reactions in sensitive individuals.

Fire-fighting measures

- Suitable extinguishing media:

The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

- Unsuitable extinguishing media:

Do not use water jet as an extinguisher, as this will spread the fire.

- Special hazards arising from the substance or mixture:

Specific hazards - Containers can burst violently or explode when heated, due to excessive pressure build-up. This product is toxic. Hazardous combustion products - Thermal decomposition or combustion products may include the following substances: Very toxic or corrosive gases or vapours.

- Advice for fire fighter: Portective actions during firefighters - Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapours and protect men stopping the leak. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. Special protective equipment for firefighters - Wear chemical protective suit. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Firefighter's clothing conforming to European standard EN469 (including helmets, protective boots and gloves) will provide a basic level of protection for chemical incidents.

Accidental release measures

- Personal precautions and Protective equipment and emergency procedures: No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary and unprotected personnel away from the spillage. Wear protective clothing as described in Section 8 of this safety data sheet. Follow precautions for safe handling described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure procedures and training for emergency decontamination and disposal are in place. Do not touch or walk into spilled material. Avoid inhalation of vapours and spray/mists. Use suitable respiratory protection. Avoid contact with skin and eyes. Avoid contact with contaminated tools and objects.

- Environmental precautions:

Slightly soluble in water. Aquatic toxicity with long lasting effects may occur. Large or frequent spills may have hazardous effects on the environment. Absorb spillage with non-combustible, absorbent material. Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Large Spillages: Inform the relevant authorities if environmental pollution occurs (sewers, waterways, soil or air).

- Methods and material for containment and cleaning up: Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. Provide adequate ventilation. Approach the spillage from upwind. Small Spillages: If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. Large Spillages: If leakage cannot be stopped, evacuate area. Flush spilled material into an effluent treatment plant, or proceed as follows. Contain and absorb spillage with sand, earth or other non-combustible material. Place waste in labelled, sealed containers. Clean contaminated objects and areas thoroughly, observing environmental regulations. The contaminated absorbent may pose the same hazard as the spilled material. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

Handling and storage

- Precautions for safe handling:

Use precautions -Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimise spills. Keep container tightly sealed when not in use. Avoid the formation of mists. This product is toxic. Immediate first aid is imperative. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Advice on general occupational hygeine - Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash at the end of each work shift and before eating, smoking and using the toilet. Change work clothing daily before leaving workplace.

- Conditions for safe storage, including any incompatibilities: Storage precautions - Store away from incompatible materials (see Section 10). Store in accordance with local regulations. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Bund storage facilities to prevent soil and water pollution in the event of spillage. The storage area floor should be leak-tight, jointless and not absorbent. Storage class - toxic storage.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

2810

Shipping information

Proper shipping name and description:

TOXIC LIQUID, ORGANIC, N.O.S.

Chemical name:

Reaction mass of N,N,N',N'-tetrabutylmethylenediamine and dibutylamine

Class or division:

Class 6: Toxic and infectious substances; Division 6.1

Packing group:

Packing group III: Substances presenting low danger

Labels:

6.1

Special provisions / remarks

Special provisions:

274
614

Inland waterway transport (UN RTDG/ADN(R))

UN number:

2810

Shipping information

Proper shipping name and description:

TOXIC LIQUID, ORGANIC, N.O.S.

Chemical name:

Reaction mass of N,N,N',N'-tetrabutylmethylenediamine and dibutylamine

Class or division:

Class 6: Toxic and infectious substances; Division 6.1

Packing group:

Packing group III: Substances presenting low danger

Labels:

6.1

Special provisions / remarks

Special provisions:

274
614

Marine transport (UN RTDG/IMDG)

UN number:

2810

Shipping information

Proper shipping name and description:

TOXIC LIQUID, ORGANIC, N.O.S.

Chemical name:

Reaction mass of N,N,N',N'-tetrabutylmethylenediamine and dibutylamine

Class or division:

Class 6: Toxic and infectious substances; Division 6.1

Packing group:

Packing group III: Substances presenting low danger

Labels:

6.1

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

2810

Shipping information

Proper shipping name and description:

TOXIC LIQUID, ORGANIC, N.O.S.

Chemical name:

Reaction mass of N,N,N',N'-tetrabutylmethylenediamine and dibutylamine

Class or division:

Class 6: Toxic and infectious substances; Division 6.1

Packing group:

Packing group III: Substances presenting low danger

Labels:

6.1

Remarks

SpecialProvisions

Exposure controls / personal protection

1. Technical protection measures and Organisational protection measures  - Provide adequate ventilation and respiratory equipment. Personal, workplace environment or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimise worker exposure. Personal protective equipment should be used if worker exposure is possible. Ensure control measures are regularly inspected and maintained. Ensure operatives are trained to minimise exposure.

2. Hand protection - Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with European Standard EN374. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended.

3. Feet protection - Appropriate footwear and additional protective clothing complying with an approved standard should be worn if a risk assessment indicates skin contamination is possible.

4. Body protection - Appropriate footwear and additional protective clothing complying with an approved standard should be worn if a risk assessment indicates skin contamination is possible.

5. Eye protection - Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Personal protective equipment for eye and face protection should comply with European Standard EN166. Wear tight-fitting, chemical splash goggles or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

6. Respiratory protection - Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective equipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fits tightly and the filter is changed regularly. Gas and combination filter cartridges should comply with European Standard EN14387. Full face mask respirators with replaceable filter cartridges should comply with European Standard EN136. Half mask and quarter mask respirators with replaceable filter cartridges should comply with European Standard EN140.

7. Hygeine measures - Provide eyewash station and safety shower. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment and the work area every day. Good personal hygiene procedures should be implemented. Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. Preventive industrial medical examinations should be carried out. Warn cleaning personnel of any hazardous properties of the product.

8. Environemental exposure controls - Keep container tightly sealed when not in use. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

1. Reactivity

- N/A

2. Chemical stability

- Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions

3. Possibility of hazardous reactions

- No potentially hazardous reactions known.

4. Conditions to avoid

- There are no known conditions that are likely to result in a hazardous situation.

5. Incompatible materials

- No specific material or group of materials is likely to react with the product to produce a hazardous situation.

6. Hazardous decomposition products - Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Toxic gases or vapours.

Disposal considerations

General information - The generation of waste should be minimised or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. Disposal of this product, process solutions, residues and by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any local authority requirements. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous.

Disposal methods - Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labelled with their contents. Incineration or landfill should only be considered when recycling is not feasible.