Registration Dossier
Registration Dossier
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EC number: 610-826-9 | CAS number: 52334-99-3
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
· General information: Personal protection for the First Aider.
· After inhalation: In case of unconsciousness place patient into the recovery position for transport. Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doct or if symptoms persist.
· After skin contact: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
· After eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Consult an eye specialist.
· After swallowing: Rinse mouth and drink plenty of water. IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
Most important symptoms and effects, both acute and delayed
Symptoms and effects are described in section 2 and 11 of the SDS.
· General information: Personal protection for the First Aider.
· After inhalation: In case of unconsciousness place patient into the recovery position for transport. Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doct or if symptoms persist.
· After skin contact: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
· After eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Consult an eye specialist.
· After swallowing: Rinse mouth and drink plenty of water. IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
Most important symptoms and effects, both acute and delayed
Symptoms and effects are described in section 2 and 11 of the SDS.
Fire-fighting measures
Extinguishing media
· Suitable extinguishing agents: Water spray jet, extinguishing powder, CO2, foam.
· Unsuitable extinguishing agents for reasons of safety: None
Special hazards arising from the substance or mixture
In case of fire, toxic incineration products may be released such as:
Carbon monoxide (CO)
Nitrogen oxides (NOx)
Sulphur dioxide (SO2)
Advice for firefighters
· Protective equipment: Wear self-contained breathing apparatus.
· Suitable extinguishing agents: Water spray jet, extinguishing powder, CO2, foam.
· Unsuitable extinguishing agents for reasons of safety: None
Special hazards arising from the substance or mixture
In case of fire, toxic incineration products may be released such as:
Carbon monoxide (CO)
Nitrogen oxides (NOx)
Sulphur dioxide (SO2)
Advice for firefighters
· Protective equipment: Wear self-contained breathing apparatus.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective clothing (see item 8).
Keep unprotected persons away.
Environmental precautions:
Do not allow product to enter waters without treatment in a (biological) water treatment plant. Prevent material from reaching sewage system, holes and cellars.
Methods and material for containment and cleaning up:
Collect large amounts in suitable container. Cover the rest with absorbent, mix intensively and collect mechanically.
Dispose of contaminated material as waste according to item 13. Provide adequate ventilation.
Wear protective clothing (see item 8).
Keep unprotected persons away.
Environmental precautions:
Do not allow product to enter waters without treatment in a (biological) water treatment plant. Prevent material from reaching sewage system, holes and cellars.
Methods and material for containment and cleaning up:
Collect large amounts in suitable container. Cover the rest with absorbent, mix intensively and collect mechanically.
Dispose of contaminated material as waste according to item 13. Provide adequate ventilation.
Handling and storage
Precautions for safe handling
Ensure good exhaust ventilation at the workplace.
Open and handle containers with care.
It is preferable to handle the product in a closed system.
Avoid air pollution at the workplace e.g. aerosol formation or product heating.
Risks to the safety and health of workers may not only be created by work involving chemicals but,
inter alia by work equipment and the fitting-out of work-places. Those risks shall be identified and evaluated.
· Information about protection against explosion and fire: Keep ignition sources away - do not smoke. Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers: Store in cool location.
· Information about storage in a common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep containers tightly sealed.
· Storage class: 3
Ensure good exhaust ventilation at the workplace.
Open and handle containers with care.
It is preferable to handle the product in a closed system.
Avoid air pollution at the workplace e.g. aerosol formation or product heating.
Risks to the safety and health of workers may not only be created by work involving chemicals but,
inter alia by work equipment and the fitting-out of work-places. Those risks shall be identified and evaluated.
· Information about protection against explosion and fire: Keep ignition sources away - do not smoke. Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers: Store in cool location.
· Information about storage in a common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep containers tightly sealed.
· Storage class: 3
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN1230
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN1230
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN1230
Shipping information
- Proper shipping name and description:
- METHANOL mixture
- Labels:
- 3/6.1
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN1230
Shipping information
- Proper shipping name and description:
- METHANOL mixture
- Labels:
- 3 (6.1)
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- Special precautions for user Warning: Flammable liquids.
· Kemler Number: 336
· EMS Number: F-E,S-D
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
Exposure controls / personal protection
Control parameters
· Components with critical values that require monitoring at the workplace:
67-56-1 methanol
WEL (Great Britain) Short-term value: 333 mg/m³, 250 ppm
Long-term value: 266 mg/m³, 200 ppm Sk
IOELV (European Union) Long-term value: 260 mg/m³, 200 ppm Skin
Exposure controls
· Technical protective equipment:
In case of contamination devices to rinse eyes or skin immediately under running water must be available.
· Personal protective equipment
· General protective and hygienic measures:
Use skin cream for skin protection.
Do not inhale gases/fumes/aerosols.
Avoid contact with the eyes and the skin.
Wash hands during work breaks and at the end of the shift.
Provide skin protection plan.
· Respiratory protection: Filter A/P2.
· Protection of hands: Chemical protective gloves according to DIN EN 374 with CE-labelling. Check the condition of protective gloves after each use for any
damages like holes, cuts or tears. Do not wear protective gloves longer than necessary. After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves Butyl rubber, BR
· Penetration time of glove material: Thickness: 0.5 mm; break-through time: 480 min; material: Butyl
· Gloves made of the following materials are not suitable: Gloves for mechanical protection do not provide protection against chemicals.
· Eye protection: Safety goggles with CE label.
· Body protection: Protective clothing.
· Risk management measures
The operators shall be instructed adequately.
The workplace shall be inspected regularly by competent personnel e.g. the safety representative.
· Components with critical values that require monitoring at the workplace:
67-56-1 methanol
WEL (Great Britain) Short-term value: 333 mg/m³, 250 ppm
Long-term value: 266 mg/m³, 200 ppm Sk
IOELV (European Union) Long-term value: 260 mg/m³, 200 ppm Skin
Exposure controls
· Technical protective equipment:
In case of contamination devices to rinse eyes or skin immediately under running water must be available.
· Personal protective equipment
· General protective and hygienic measures:
Use skin cream for skin protection.
Do not inhale gases/fumes/aerosols.
Avoid contact with the eyes and the skin.
Wash hands during work breaks and at the end of the shift.
Provide skin protection plan.
· Respiratory protection: Filter A/P2.
· Protection of hands: Chemical protective gloves according to DIN EN 374 with CE-labelling. Check the condition of protective gloves after each use for any
damages like holes, cuts or tears. Do not wear protective gloves longer than necessary. After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves Butyl rubber, BR
· Penetration time of glove material: Thickness: 0.5 mm; break-through time: 480 min; material: Butyl
· Gloves made of the following materials are not suitable: Gloves for mechanical protection do not provide protection against chemicals.
· Eye protection: Safety goggles with CE label.
· Body protection: Protective clothing.
· Risk management measures
The operators shall be instructed adequately.
The workplace shall be inspected regularly by competent personnel e.g. the safety representative.
Stability and reactivity
Reactivity
Up to now, no dangers resulting from a reactivity of the mixture have been identified.
Chemical stability
· Conditions to be avoided:
Before handling, the product should not be diluted or mixed with other chemicals, in order to avoid any negative influences on the ingredient(s).
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: Strong oxidising agents
Hazardous decomposition products: None, if storage and handling is done according to specification.
Up to now, no dangers resulting from a reactivity of the mixture have been identified.
Chemical stability
· Conditions to be avoided:
Before handling, the product should not be diluted or mixed with other chemicals, in order to avoid any negative influences on the ingredient(s).
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: Strong oxidising agents
Hazardous decomposition products: None, if storage and handling is done according to specification.
Disposal considerations
· Recommendation
Must be specially treated under adherence to official regulations.
Appropriate disposal operations according to Directive 2008/98/EC on waste: D 10 Incineration on land
· European waste catalogue
16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST
16 03 00 off-specification batches and unused products
16 03 05* organic wastes containing hazardous substances
HP 3 Flammable
HP 4 Irritant - skin irritation and eye damage
HP 5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity
HP 6 Acute Toxicity
· Contaminated packaging:
· Recommendation: Packaging can be reused or recycled after cleaning.
· Recommended cleaning agent: Water, if necessary with cleaning agent.
Must be specially treated under adherence to official regulations.
Appropriate disposal operations according to Directive 2008/98/EC on waste: D 10 Incineration on land
· European waste catalogue
16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST
16 03 00 off-specification batches and unused products
16 03 05* organic wastes containing hazardous substances
HP 3 Flammable
HP 4 Irritant - skin irritation and eye damage
HP 5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity
HP 6 Acute Toxicity
· Contaminated packaging:
· Recommendation: Packaging can be reused or recycled after cleaning.
· Recommended cleaning agent: Water, if necessary with cleaning agent.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
