Registration Dossier
Registration Dossier
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EC number: 604-481-3 | CAS number: 14559-13-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Inhalation
Remove from exposure to fresh air. Obtain medical attention.
Skin contact
Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. Consult a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Cunsult a physician.
Ingestion
Drink plenty of water. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
May cause sensitization by skin contact.
Indication of immediate medical attention and special treatment needed
Treatment according to symptoms.
Inhalation
Remove from exposure to fresh air. Obtain medical attention.
Skin contact
Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. Consult a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Cunsult a physician.
Ingestion
Drink plenty of water. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
May cause sensitization by skin contact.
Indication of immediate medical attention and special treatment needed
Treatment according to symptoms.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media
Water spray, foam, dry chemical, carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture
Hazardous decomposition products: SOx, COx.
Advice for firefighters
Wear self-contained breathing apparatus and protective suit.
Other information
Cool containers with water spray.
Suitable extinguishing media
Water spray, foam, dry chemical, carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture
Hazardous decomposition products: SOx, COx.
Advice for firefighters
Wear self-contained breathing apparatus and protective suit.
Other information
Cool containers with water spray.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Evacuate personnel to safe areas. Remove all sources of ignition. Avoid contact with the skin. Use personal protective equipment.
Environmental precautions
Should not be released into the aquatic environment or drains.
Methods and materials for containment and cleaning up
Adsorption in inert material (e.g. sand or universal binder). Take up mechanically and collect in suitable container for disposal. Dispose of as special waste in compliance with local and national regulations.
Reference to other sections
Information regarding personal protective equipment, see section "Exposure controls/personal protection". Information regarding waste disposal, see Section "Disposal considerations".
Evacuate personnel to safe areas. Remove all sources of ignition. Avoid contact with the skin. Use personal protective equipment.
Environmental precautions
Should not be released into the aquatic environment or drains.
Methods and materials for containment and cleaning up
Adsorption in inert material (e.g. sand or universal binder). Take up mechanically and collect in suitable container for disposal. Dispose of as special waste in compliance with local and national regulations.
Reference to other sections
Information regarding personal protective equipment, see section "Exposure controls/personal protection". Information regarding waste disposal, see Section "Disposal considerations".
Handling and storage
This substance is handled under strictly controlled conditions in accordance with REACH regulation Article 17 (3) for on-site isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing site.
Precautions for safe handling
Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or ehhaust in work rooms. Do not breathe gas/fumes/vapour/spray. Use personal protective equipment. Provide work rooms with safety shower and eye wash bottle with pure water. Have a shower after handling the product.
Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a cool, well-ventilated place. Keep at temperatures above 0°C. Protect from light. Keep container dry. Keep away from heat and sources of ignition.
Specific end use(s)
No data.
Precautions for safe handling
Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or ehhaust in work rooms. Do not breathe gas/fumes/vapour/spray. Use personal protective equipment. Provide work rooms with safety shower and eye wash bottle with pure water. Have a shower after handling the product.
Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a cool, well-ventilated place. Keep at temperatures above 0°C. Protect from light. Keep container dry. Keep away from heat and sources of ignition.
Specific end use(s)
No data.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3082
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- -
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid, n.o.s. (Protiothiophene)
- Chemical name:
- Methyl 4,5-dimethyl-3-thiophenecarboxylate
- Labels:
- 90
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid n.o.s. (Protiothiophene)
- Chemical name:
- Methyl 4,5-dimethyl-3-thiophenecarboxylate
- Labels:
- 90
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
This substance is handled under strictly controlled conditions in accordance with REACH regulation Article 17 (3) for on-site isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing site.
Control parameters
Other information on limit values
No information available.
Limit values on other countries
No data available.
DNELS
Not known
PNECS
Not known
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Do not breathe vapours. Have a wash after handling the product. Take off all contaminated clothing immediately. Wash contaminated clothing before re-use.
Individual protection measures
Respiratory protection
Respirator with A/P2-filter. ABEK-P3 is applicable. Fresh air blower if needed.
Hand protection
Chemical-resistant gloves; For example Butyl-gloves. Break through times: no data available.
Eye/face protection
Safety goggles / face-shield.
Skin protection
Protective suit.
Environmental exposure controls
Should not be released into the environment.
Control parameters
Other information on limit values
No information available.
Limit values on other countries
No data available.
DNELS
Not known
PNECS
Not known
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Do not breathe vapours. Have a wash after handling the product. Take off all contaminated clothing immediately. Wash contaminated clothing before re-use.
Individual protection measures
Respiratory protection
Respirator with A/P2-filter. ABEK-P3 is applicable. Fresh air blower if needed.
Hand protection
Chemical-resistant gloves; For example Butyl-gloves. Break through times: no data available.
Eye/face protection
Safety goggles / face-shield.
Skin protection
Protective suit.
Environmental exposure controls
Should not be released into the environment.
Stability and reactivity
Reactivity
No spesific reactivity known when stored and handled according to prescribed instructions.
Chemical stability
No data available.
Possibility of hazardous reactions
Not if used and storage under normal recommended conditions.
Conditions to avoid
Keep away from heat and sources of ignition.
Incompatible materials
Strong oxidizing agents. Hydrolyzes with alkali hydroxides.
Hazardous decomposition products
Carbon oxides, sulfur oxides (COx, SOx).
No spesific reactivity known when stored and handled according to prescribed instructions.
Chemical stability
No data available.
Possibility of hazardous reactions
Not if used and storage under normal recommended conditions.
Conditions to avoid
Keep away from heat and sources of ignition.
Incompatible materials
Strong oxidizing agents. Hydrolyzes with alkali hydroxides.
Hazardous decomposition products
Carbon oxides, sulfur oxides (COx, SOx).
Disposal considerations
Waste treatment methods
Dispose of as special waste in compliance with local and national regulations.
Waste from residues/unused products
Dispose of residues and contaminated packaging as a special waste in compliance with local and national regulations.
Dispose of as special waste in compliance with local and national regulations.
Waste from residues/unused products
Dispose of residues and contaminated packaging as a special waste in compliance with local and national regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
