Registration Dossier
Registration Dossier
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EC number: 802-236-7 | CAS number: 1289090-35-2
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Skin contact: Wash with plenty of soap and water. Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
CONTACT WITH THE HOT MELT: Cooling immediately with plenty of water. Do not
remove product crusts which may have formed neither forcibly nor by applying any
solvents to the skin involved. In order to obtain medical care for possible burns and
for a smooth cleansing of the skin, seek medical advice immediately.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Skin contact: Wash with plenty of soap and water. Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
CONTACT WITH THE HOT MELT: Cooling immediately with plenty of water. Do not
remove product crusts which may have formed neither forcibly nor by applying any
solvents to the skin involved. In order to obtain medical care for possible burns and
for a smooth cleansing of the skin, seek medical advice immediately.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: This material is toxic to aquatic life with long lasting effects. Fire water contaminated
with this material must be contained and prevented from being discharged to any
waterway, sewer or drain.
Hazardous thermal decomposition products: No specific data.
Advice for firefighters
Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: This material is toxic to aquatic life with long lasting effects. Fire water contaminated
with this material must be contained and prevented from being discharged to any
waterway, sewer or drain.
Hazardous thermal decomposition products: No specific data.
Advice for firefighters
Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency responders: If specialised clothing is required to deal with the spillage, take note of any
information on suitable and unsuitable materials.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. Collect spillage.
Methods and material for containment and cleaning up
Small spill: Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA
filter will reduce dust dispersal. Place spilled material in a designated, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water courses,
basements or confined areas. Approach the release from upwind. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via a licensed waste
disposal contractor.
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency responders: If specialised clothing is required to deal with the spillage, take note of any
information on suitable and unsuitable materials.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. Collect spillage.
Methods and material for containment and cleaning up
Small spill: Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA
filter will reduce dust dispersal. Place spilled material in a designated, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water courses,
basements or confined areas. Approach the release from upwind. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via a licensed waste
disposal contractor.
Handling and storage
Manufacture and use of this chemical intermediate takes place under strictly controlled conditions, as described in Art. 17/18 REACH. The substance is rigorously contained during manufacturing and use and appropriate risk management measures including PPE (i.g. during charging or sampling) are applied. Occupational exposure is reduced to a minimum and well controlled by measurements. A management system covering all general aspects of a chemical production is in place, especially cleaning and maintenance of plants and equipment. An authorisation scheme based on instructions covering the whole process ensures that only trained and authorised staff handles the substance.
Precautions for safe handling
Protective measures: Put on appropriate personal protective equipment. Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid release to the environment. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Empty containers retain product residue and can be hazardous. The product is
registered with strictly controlled conditions as defined in Article 17(3) or 18(4) of
regulation (EC) no. 1907/2006 (REACH Regulation) and must therefore be handled
as such. Refer to the industry guidance prepared by Concawe/Cefic/EFCG for advice
on the confirmation of strictly controlled conditions.
Advice on general occupational hygiene:7.2 Conditions for safe storage, including any incompatibilities
7.3 Specific end use(s)
Recommendations :
Industrial sector specific :
solutions
Not available.
Not available.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas.
Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabelled containers. Use
appropriate containment to avoid environmental contamination. Store in a dry place.
Seveso Directive - Reporting thresholds (in tonnes)
Danger criteria
Category E2: Hazardous to the aquatic environment - Chronic 2
Notification and MAPP threshold: 200
Safety report threshold: 500
Category C9ii: Toxic for the environment
Notification and MAPP threshold: 200
Safety report threshold: 500
Remarks: Hot melt; risk of skin burns. Use original container.
Precautions for safe handling
Protective measures: Put on appropriate personal protective equipment. Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid release to the environment. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Empty containers retain product residue and can be hazardous. The product is
registered with strictly controlled conditions as defined in Article 17(3) or 18(4) of
regulation (EC) no. 1907/2006 (REACH Regulation) and must therefore be handled
as such. Refer to the industry guidance prepared by Concawe/Cefic/EFCG for advice
on the confirmation of strictly controlled conditions.
Advice on general occupational hygiene:7.2 Conditions for safe storage, including any incompatibilities
7.3 Specific end use(s)
Recommendations :
Industrial sector specific :
solutions
Not available.
Not available.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas.
Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabelled containers. Use
appropriate containment to avoid environmental contamination. Store in a dry place.
Seveso Directive - Reporting thresholds (in tonnes)
Danger criteria
Category E2: Hazardous to the aquatic environment - Chronic 2
Notification and MAPP threshold: 200
Safety report threshold: 500
Category C9ii: Toxic for the environment
Notification and MAPP threshold: 200
Safety report threshold: 500
Remarks: Hot melt; risk of skin burns. Use original container.
Transport information
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SpecialProvisionsopen allclose all
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
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Remarksopen allclose all
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SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure limit values : Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
Exposure controls
Appropriate engineering controls: In cases of accident and where waste is generated, procedural and/or control
technologies shall be used to minimise emissions and the resulting exposure during
purification or cleaning and maintenance procedures. Procedural and control
technologies shall be used that minimise emission and any resulting exposure. The
substance shall be rigorously contained by technical means during its whole lifecycle
including manufacture, purification, cleaning and maintenance of equipment,
sampling, analysis, loading and unloading of equipment or vessels, waste disposal
or purification and storage.
Individual protection measures
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Recommended: Tightly-fitting goggles / face protection shield
Skin protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if product contact cannot be
excluded. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for
different glove manufacturers. In the case of mixtures, consisting of several
substances, the protection time of the gloves cannot be accurately estimated. After
contamination with product change the gloves immediately and dispose of them
according to relevant national and local regulations
Recommended: (< 1 hour) When handling hot material, wear heat-resistant
protective gloves that are able to withstand the temperature of molten product.
Other skin protection: Personal protective equipment for the body should be approved by a specialist before handling this product.
Recommended: chemical-resistant protective suit
Respiratory protection: If exposure cannot be ruled out, e.g. during product transfer, sampling or
maintenance, a well-fitting respiratory mask conforming to standards or well-fitting
respiratory device conforming to standards must be worn. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Recommended: Full mask with type ABEK filter
Environmental exposure controls: In some cases, special waste water treatment, fume scrubbers, filters or
engineering modifications to the process equipment will be necessary to reduce
emissions to acceptable levels.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
Exposure controls
Appropriate engineering controls: In cases of accident and where waste is generated, procedural and/or control
technologies shall be used to minimise emissions and the resulting exposure during
purification or cleaning and maintenance procedures. Procedural and control
technologies shall be used that minimise emission and any resulting exposure. The
substance shall be rigorously contained by technical means during its whole lifecycle
including manufacture, purification, cleaning and maintenance of equipment,
sampling, analysis, loading and unloading of equipment or vessels, waste disposal
or purification and storage.
Individual protection measures
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Recommended: Tightly-fitting goggles / face protection shield
Skin protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if product contact cannot be
excluded. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for
different glove manufacturers. In the case of mixtures, consisting of several
substances, the protection time of the gloves cannot be accurately estimated. After
contamination with product change the gloves immediately and dispose of them
according to relevant national and local regulations
Recommended: (< 1 hour) When handling hot material, wear heat-resistant
protective gloves that are able to withstand the temperature of molten product.
Other skin protection: Personal protective equipment for the body should be approved by a specialist before handling this product.
Recommended: chemical-resistant protective suit
Respiratory protection: If exposure cannot be ruled out, e.g. during product transfer, sampling or
maintenance, a well-fitting respiratory mask conforming to standards or well-fitting
respiratory device conforming to standards must be worn. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Recommended: Full mask with type ABEK filter
Environmental exposure controls: In some cases, special waste water treatment, fume scrubbers, filters or
engineering modifications to the process equipment will be necessary to reduce
emissions to acceptable levels.
Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid No specific data.
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Chemical stability The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid No specific data.
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Disposal considerations
Product
Methods of disposal: The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal:
The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.
Methods of disposal: The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal:
The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
