Registration Dossier
Registration Dossier
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EC number: 237-658-5 | CAS number: 13889-96-8
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact: Take off contaminated clothing. Wash off with soap and plenty of water.
Consult a physician.
In case of eye contact: Hold eyes open and rinse slowly and gently with water for 15-20 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a
doctor.
If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water.
Consult a physician.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation: causes jerky breathing, coughing, chest and headaches. Pneumonia can
develop.
Ingestion: nausea, headache, vomiting and abdominal pain. There's a blood dump
possible.
Getting on the skin: causes severe redness and irritation. Small blisters and abscesses
quickly infested on red skin develop. It can cause chemical burns.
4.3. Indication of any immediate medical attention and special treatment needed
Symptomatic treatment should be used. In severe cases, it is necessary to protect the
injured from pulmonary edema. Keep the injured person at rest and warm, prevent
infections.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
5.2. Special hazards arising from the substance or mixture
During a fire, smoke may contain the original material in addition to combustion products of
varying composition which may be toxic and/or irritating. Combustion products may include and
are not limited to: Carbon oxides, Sulfur oxides and Hydrochloric acid.
5.3. Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary. Cool containers in fire with
water spray. Do not canalize spent water from firefighting but collect and treat according to local
regulations. Caution should be placed on water entering storage because there is a risk of
decomposition, rapid gas development and explosion.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal protective equipment must be used. Inhalation of vapours and skin access should be
avoided. Adequate ventilation must be provided. For personal protection, see Part 8.
6.2. Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
6.3. Methods and materials for containment and cleaning up
A larger quantity of spilled products must be delimited and pumped into an appropriate
container. Minor spills with dry sand or other neutral and non-aqueous material should be
siphoned off and treated as hazardous waste. The product can be neutralized with an aqueous
ammonia solution.
Handling and storage
7.1. Precautions for safe handling
Avoid contact with the skin and contact with the eyes. The formation of mist and
aerosol should be avoided. Do not eat, drink or smoke while working. Before eating,
drinking and smoking, wash your face and hands. Care should be taken when opening
a closed container, as any internal pressure may cause the material to splash out. For
precautionary measures, see Chapter 2.2
7.2. Conditions for safe storage, including any incompatibilties
The container should be tightly closed in a dry and well-ventilated place. Store in a
cool place. It should be kept away from food, drinks and animal feed. The introduction
of moisture into the storage tank or container can cause a violent reaction,
decomposition, increase in pressure, explosion.
Packaging: metal casks coated with epoxy resin or plastic containers.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- none
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Constituents with workplace control parameters: None. There are not any DNEL or PNEC value
established.
8.2. Exposure controls
Appropriate engineering controls
It shall be treated on the basis of good industrial health and safety practice. Technical
measures: Ventilation is required indoors. Emergency showers and eye rinses must be
available. The vapours formed must be absorbed.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166.
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws. Wash and dry
hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425
and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific
workplace.
Respiratory protection
For higher level protection use type ABEK (EU EN 143) respirator cartridges. Use respirators
and components tested and approved under appropriate government standards such as CEN
(EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
Stability and reactivity
10.1. Reactivity
Under normal storage conditions no decomposition occurs.
10.2. Chemical stability
Under normal storage conditions no decomposition occurs.
10.3. Possibility of hazardous reactions
Not known
10.4. Conditions to avoid
Wet environment
10.5. Incompatible materials
Water, heavy metal salts.
10.6. Hazardous decomposition products
Under normal storage conditions no decomposition occurs
Disposal considerations
Waste treatment methods
Product
Offer surplus and non-recyclable product to a licensed disposal company. Burn in a chemical
incinerator with afterburner and absorber.
Contaminated packaging
Dispose of as hazardous waste.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
