2-bromo-4'-chloro-2'-(o-fluorobenzoyl)acetanilide

Guidance on Safe Use

First-aid measures

Description of first aid measures:

Pay attention to self-protection.

Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilized position and covered.

Do not leave victims unattended.

If the casualty is unconscious: Place the victim in the recovery position.

Inhalation:

Inhalation is possible if aerosols, mists, dusts, or smoke form.

Move victims into fresh air.

With labored breathing: Provide with oxygen. Consult a doctor.

If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.

Skin contact:

Wash off affected area immediately with plenty of water for at least 15 minutes.

If symptoms persist, consult a physician for treatment.

Eye contact:

With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.

In case of persistent discomfort: Consult an ophthalmologist.

Ingestion:

Rinse mouth.

Immediately give large quantities of water to drink.

Obtain medical attention.

Most important symptoms and effects, both acute and delayed:

Symptoms:

None known

Hazards:

Other dangerous properties can not be excluded.

Indication of any immediate medical attention and special treatment needed:

This substance has no remarkable acute health hazard potential. Acute health damage is therefore not to be expected.

Fire-fighting measures

Extinguishing media:

Suitable extinguishing media:

Water spray, foam, CO2, dry powder. Sand

Unsuitable extinguishing media:

Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture:

Hazard-determining flue gases might develop in case of fire:

nitrogen oxides (NOx)

hydrogen bromide

hydrogen chloride

Hydrogen fluoride

Carbon monoxide

Carbon dioxide (CO2)

Advice for firefighters:

Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.

Water used to extinguish fire should not enter drainage systems, soil or stretches of water.

In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely.

Cool down container with a water jet from a safe distance.

Keep out unprotected persons.

wear a self contained respiratory apparatus

full protective suit

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Keep unauthorized persons away.

Environmental precautions:

Prevent substance from entering soil, natural bodies of water and sewer systems.

If the product contaminates rivers and lakes or drains inform respective authorities.

Observe regulations on prevention of water pollution (check, dam up, cover up).

Methods and material for containment and cleaning up:

Pick up mechanically. Collect in suitable containers.

To absorb spilled substance an approved industrial vacuum cleaner is recommended. If necessary, the spilled substance should be moistened.

Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.

Disposal according to local authority regulations.

Clean contaminated surface thoroughly.

Handling and storage

Precautions for safe handling:

Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.

Ensure that apparatus and pipelines are free from leaks. Do not ventilate into the open.

Dedicated loading/unloading stations required.

Avoid residues of the product on the containers.

Conditions for safe storage, including any incompatibilities:

Advice on protection against fire and explosion:

When using do not smoke.

Take precautionary measures against static discharges.

Storage:

Store in original container.

Keep in a dry, cool and well-ventilated place.

Further information:

In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.

German storage class:

13 - Non Combustible Solids

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone)

Chemical name:

2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone

Language:

English

Labels:

9

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone)

Chemical name:

2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone

Language:

English

Labels:

9

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone)

Chemical name:

2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone

Labels:

9

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3077

Shipping information

Proper shipping name and description:

Environmentally hazardous substance, solid, n.o.s. (2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone)

Chemical name:

2-Bromoacetamido-2'-fluoro-5-chlorobenzophenone

Labels:

9MI

Remarks

Additional transport information

Additional information

Special provisions / remarks / other:

Combination traffic :
Labelling of containers / shipping units following main product run as per sea or air transport regulations

Exposure controls / personal protection

Exposure controls:

Engineering measures:

Provide for installation of emergency shower and eye bath.

Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.

Do not lead exhaust air back to workplace areas unfiltered.

Exhaust filter or scrubber: exhaust air filter (HEPA-filter)

Do not add wastewater to a biological wastewater treatment plant

Dispose of waste gases in a suitable incineration plant.

In case of dissolved solids:

Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.

Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).

All precautionary measures indicated have to be observed.

Exposure controls:

The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.

Personal protective equipment:

Respiratory protection:

Accidental release measures: use respiratory equipment with suitable filter (filter type P3) or wear a self contained respiratory apparatus

Note time limit for wearing respiratory protective equipment.

Hand protection:

Glove material: Nitrile, for example, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany

Material thickness: 0.11 mm

Method: DIN EN 374

Accidental release measures

Glove material: Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany

Material thickness: 0.65 mm

Method: DIN EN 374

Selection of protective gloves to meet the requirements of specific workplaces.

Suitability for specific workplaces should be clarified with protective glove manufacturers.

The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.

Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).

Eye protection:

Safety glasses with side-shields conforming to EN166

Accidental release measures: goggles

Skin and body protection: suitable protective clothing - Use disposable clothing if appropriate.

Hygiene measures:

Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.

Remove immediately all contaminated clothing.

Provide adequate ventilation.

Preventive skin protection is recommended.

Avoid contact with skin, eyes, and clothing.

Protective measures

Risk assessment and risk monitoring of all work places required.

Health, Safety and Emergency Management System recommended.

Written approval necessary in case of non-routine jobs, e.g. maintenance activities.

Regular safety training is a must.

All precautionary measures indicated have to be observed.

The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).

It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.

Environmental exposure controls:

In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.

Stability and reactivity

Reactivity:

No further information available

Chemical stability:

No further information available

Possibility of hazardous reactions:

No dangerous reaction known under conditions of normal use.

No special measures are required.

Conditions to avoid:

No decomposition if used as directed.

Take precautionary measures against static discharges.

Avoid shock and friction.

Incompatible materials:

alkalis, Ammonia, Amines, Metals

Hazardous decomposition products:

No hazardous decomposition products known.

Disposal considerations

Waste treatment methods:

Product:

Strictly controlled conditions during disposal or treatment to air, wastewater and waste.

Do not add wastewater to a biological wastewater treatment plant

Bring wastewater containing AOX for professional disposal.

Bring used exhaust air filter for incineration

Disposal according to local authority regulations.

Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.

Uncleaned packaging:

Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.

Waste Key Number:

The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.