Registration Dossier
Registration Dossier
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EC number: 467-300-5 | CAS number: -
Guidance on Safe Use
Administrative data
First-aid measures
Emergency measure - Inhalation: Move to fresh air. If you feel unwell, seek medical advice.
Emergency measure - Eyes: Rinse immediately with gently running water for 15 minutes,
maintaining eyelids open. Consult an ophthalmologist or a
physician.
Emergency measure - Skin: After contact with skin, wash immediately with plenty of
water and soap.
Emergency measure - Ingestion: Only as long as the patient is fully conscious: wash mouth
and have the victim drink copious amounts of water (often
vomiting will be induced). Consult a physician immediately.
Fire-fighting measures
Recommended extinguishing agent: The on-site fire crews would tackle any localized fire with
a dry powder extinguisher. If a major fire is involved, the
building sprinkler system would automatically activate. The
process drainage system is arranged such that all process
effluent is captured within a catchment pit which prevents
transfer to the site effluent treatment plant (ETP). As
required, the contents of this pit can be transferred to a
holding tank for subsequent analysis and despatch for
incineration. If there is a risk of fume inhalation, the
firemen would wear breathing apparatus and fire-fighting
PPE.
Product arising from burning: Phosphorus oxides, phosphine, nickel oxides, carbon
oxides, hydrogen chloride.
Product determined by test: N
Protective equipment: Wear self-contained breathing apparatus and protection suit.
Accidental release measures
Emergency measures in case of spillage: In the event of spillage, the solid material will be
collected in dry form, sealed in a lined drum, labelled and
incinerated. The subsequent water washings are isolated,
analysed and treated in the waste treatment unit or
incinerated depending on concentration.
Liquid spillages would be isolated in catchment pits within
the manufacturing area.
Handling and storage
Handling: Engineering:
Local exhaust ventilation with HEPA filtration
PPE: Operators to wear;
Nitrile gloves in line with EN 388 and EN 374
Chemical protective suit in line with EN 465
Protective footwear to EN345
Safety glasses in line with EN1661
Air-fed hood tested in line with EN141-3, wherever there is
danger from open plant i.e. risk of exposure to an oxygen-
deficient atmosphere (ODA). If there is no danger from an
ODA, use a Tornado powered respirator with filter tested in
line with EN141-3
Storage: The enclosed substance, suitably labelled, will be stored
under cover in a warehouse unit at ambient temperature until
required for use in the production building. Only the
required amount for one batch will be transferred to the
production building at any one time.
Packaging of the substance and or preparation: The bis(dppp)nickel(II) chloride solid will be supplied in
polythene bags, 4 kg nett weight within a steel drum. There
will be 15 bags, nett weight 60 kgs within each 100 L steel
drum.
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
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Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
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Special provisions / remarks
- Remarks:
- Transport code: RID/ADR: 6.1/T3, ICAO/IATA-DGR: 6.1, IMDG-Code: 6.1
Transport: Fork lift or hand lift trucks on pallet.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Contains:
DIMETHYL FORMAMIDE
Occupational Exposure Controls
Industrial Hygiene Avoid contact with skin and eyes.
Laboratory:
Respiration : Disposable fine dust protection mask (EN149)
Eye : Safety glasses (EN166)
Hand : Disposable gloves (EN374)
Additional protection : Lab coat
Personal Protection Measures
Respiration : Approved respirator or airhood
Filter : Combination filter
Eye : Wear approved safety glasses or visor
Hand : Butoject gloves (898) give >480 minutes protection
Additional protection : Lapren gloves (706) give 60 minutes protection
Camatril gloves(730/732/733) give 10 minutes protection
Wear chemical protective suit tested in line with EN 369/374-3
In daily work please be aware that the using time depends on several factors and can be shorter than the officially tested permeation time.
The Personal protective equipment (PPE) specified for a particular task should be that chosen as a result of a risk assessment, which takes into account such factors as the nature of the task, the hazards associated with the material and the quantities handled. Generally, this information gives advice on PPE to be worn where medium/large quantities are handled and/or other controls (e.g. ventilation) are not in place, or for emergency situations.
Stability and reactivity
Danger other than fire: not known.
Chemical reaction with water: not known.
Dust explosion: Not known.
Dust explosion determined by test: N
Disposal considerations
Industry - Possibility of recovery/recycling: There is no provision for recovery of any materials from the
process.
Industry - Possibility of neutralisation: The nickel catalyst will be converted to nickel hydroxide
during the process. This nickel compound will be contained
in an aqueous waste stream which will be collected and sent
for incineration at a licensed incineration UK facility.
Industry - Possibility of destruction: controlled discharge: The nickel catalyst will be converted to nickel hydroxide
during the process. This nickel compound will be contained
in an aqueous waste stream which will be collected and sent
for incineration at a licensed incineration UK facility.
Industry - Possibility of destruction - incineration: The nickel catalyst will be converted to nickel hydroxide
during the process. This nickel compound will be contained
in an aqueous waste stream which will be collected and sent
for incineration at a licensed incineration UK facility.
Industry - Possibility of destruction - water purification: not applicable.
Industry - Possibility of destruction - other: not applicable.
Public at large - Possibility of recovery/recycling: not applicable.
Public at large - Possibility of neutralisation: not applicable.
Public at large - Possibility of destruction: controlled discharge: not applicable.
Public at large - Possibility of destruction - incineration: not applicable.
Public at large - Possibility of destruction - water purification: not applicable.
Public at large - Possibility of destruction - others: not applicable.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
