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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

4.1 Description of first aid measures
· General information:
Get medical advice/attention if you feel unwell.
Immediately remove any clothing soiled by the product.
Take affected persons out of danger area and lay down.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed Illness
· 4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
For specialist advice physicians should contact the Poisons Information Service.

Fire-fighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Sulphur dioxide (SO₂)
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Do not inhale explosion gases or combustion gases.

Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Avoid formation of dust.
Wear protective clothing.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Pick up mechanically.
Ensure adequate ventilation.
Dispose contaminated material as waste according to item 13.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

Handling and storage

· 7.1 Precautions for safe handling
Prevent formation of dust.
Ensure good ventilation/exhaustion at the workplace.
Use appropriate industrial vacuum cleaners or central vacuum systems for dust removal.
Dust can combine with air to form an explosive mixture.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
· Information about storage in one common storage facility: Do not store together with acids.
· Further information about storage conditions:
Keep container tightly sealed.
Store in dry conditions.
· 7.3 Specific end use(s)
Additive for composites.
Additive for lubricants

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

· Additional information about design of technical facilities:
local ventilation
No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Do not inhale dust / smoke / mist.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Use skin protection cream for skin protection.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
Short term filter device:
Filter P2
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Use gloves of stable material (e.g. Nitrile) - if necessary tricoted to improve the wearability.
· Material of gloves
Nitrile rubber, NBR
Recommended thickness of the material: 0,2 mm
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Safety glasses
· Body protection: Protective work clothing

Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.
· 10.3 Possibility of hazardous reactions
With strong oxidizing agents formation of sulphur dioxide
With concentrated acids formation of hydrogen sulphide
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials:
strong acids
strong oxidizing agents
· 10.6 Hazardous decomposition products:
Sulphur dioxide
Hydrogen sulphide

Disposal considerations

· 13.1 Waste treatment methods
· Recommendation Disposal must be made according to official regulations
· European waste catalogue
06 06 02 wastes containing dangerous sulphides
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.