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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Identification

Chemical structure
Display Name:
[1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
EC Number:
255-965-2
EC Name:
[1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
CAS Number:
42844-93-9
Molecular formula:
C29H18N4NiO3
IUPAC Name:
Nickel, [1,3-dihydro-5,6-bis[[[2-(hydroxy-kO)-1-naphthalenyl]methylene]amino-kN]-2H-benzimidazol-2-onato(2-)]-, (SP-4-2)-

Type of Substance

Composition:
mono-constituent substance
Origin:
organic

Substance Identifiers open all close all

  • Pigment Orange 68
  • Compositions

    Boundary Composition(s) open all close all

    State Form:
    solid: nanoform
    Degree of purity:
    >= 97.5 - <= 100 % (w/w)


    Constituent 1
    Chemical structure
    Reference substance name:
    [1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
    EC Number:
    255-965-2
    EC Name:
    [1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
    CAS Number:
    42844-93-9
    Molecular formula:
    C29H18N4NiO3
    IUPAC Name:
    Nickel, [1,3-dihydro-5,6-bis[[[2-(hydroxy-kO)-1-naphthalenyl]methylene]amino-kN]-2H-benzimidazol-2-onato(2-)]-, (SP-4-2)-
    Impurity 1
    Chemical structure
    Reference substance name:
    2-hydroxy-1-naphthaldehyde
    EC Number:
    211-902-0
    EC Name:
    2-hydroxy-1-naphthaldehyde
    CAS Number:
    708-06-5
    Molecular formula:
    C11H8O2
    IUPAC Name:
    2-hydroxy-1-naphthaldehyde
    Impurity 2
    Chemical structure
    Reference substance name:
    N,N-dimethylformamide
    EC Number:
    200-679-5
    EC Name:
    N,N-dimethylformamide
    CAS Number:
    68-12-2
    Molecular formula:
    C3H7NO
    IUPAC Name:
    N,N-dimethylformamide

    Characterisation of nanoforms

    Type of information reported:
    single nanoform
    Name of nanoform:
    C.I. Pigment Orange 68 - joint submission

    Shape

    Shape descriptionopen allclose all
    Shape category:
    spheroidal
    Shape:
    cubic
    Pure shape:
    no
    Range:
    > 5 - < 80 %
    Shape category:
    spheroidal
    Shape:
    spherical
    Pure shape:
    no
    Range:
    > 0 - < 30 %
    Shape category:
    elongated
    Shape:
    rod
    Pure shape:
    yes
    Range:
    > 5 - < 80 %

    Particle size distribution and range

    Particle size distribution and rangeopen allclose all
    Shape category:
    spheroidal
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.02 - <= 0.07 μm
    Percentile:
    D50
    Range:
    >= 0.035 - <= 0.115 μm
    Percentile:
    D90
    Range:
    >= 0.065 - <= 0.165 μm
    Additional information:
    the particle size distribution relates to both shape categories
    Fraction of constituent particles in the size range 1-100 nm:
    >= 60 - <= 100 %
    Shape category:
    elongated
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.02 - <= 0.07 μm
    Percentile:
    D50
    Range:
    >= 0.035 - <= 0.115 μm
    Percentile:
    D90
    Range:
    >= 0.065 - <= 0.165 μm
    Range of length:
    >= 0.1 - <= 0.6 μm
    Range of aspect ratio (:1):
    >= 3 - <= 5.8
    Additional information:
    the particle size distribution relates to both shape categories
    Fraction of constituent particles in the size range 1-100 nm:
    >= 60 - <= 100 %

    Crystallinity

    Structures
    Structure:
    crystalline
    Name:
    C.I. Pigment Orange 68
    Pure structure:
    yes

    Specific surface area

    Range of specific surface area:
    >= 10 - <= 50 m²/g

    Surface functionalisation / treatment

    Surface treatment applied:
    no

    Legal Entity Composition(s) open all close all

    State Form:
    solid: nanoform
    Degree of purity:
    >= 97.5 - <= 100 % (w/w)


    Constituent 1
    Chemical structure
    Reference substance name:
    [1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
    EC Number:
    255-965-2
    EC Name:
    [1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
    CAS Number:
    42844-93-9
    Molecular formula:
    C29H18N4NiO3
    IUPAC Name:
    Nickel, [1,3-dihydro-5,6-bis[[[2-(hydroxy-kO)-1-naphthalenyl]methylene]amino-kN]-2H-benzimidazol-2-onato(2-)]-, (SP-4-2)-
    Impurity 1
    Chemical structure
    Reference substance name:
    2-hydroxy-1-naphthaldehyde
    EC Number:
    211-902-0
    EC Name:
    2-hydroxy-1-naphthaldehyde
    CAS Number:
    708-06-5
    Molecular formula:
    C11H8O2
    IUPAC Name:
    2-hydroxy-1-naphthaldehyde
    Impurity 2
    Chemical structure
    Reference substance name:
    N,N-dimethylformamide
    EC Number:
    200-679-5
    EC Name:
    N,N-dimethylformamide
    CAS Number:
    68-12-2
    Molecular formula:
    C3H7NO
    IUPAC Name:
    N,N-dimethylformamide

    Characterisation of nanoforms

    Type of information reported:
    single nanoform
    Name of nanoform:
    C.I. Pigment Orange 68 - joint submission

    Shape

    Shape descriptionopen allclose all
    Shape category:
    spheroidal
    Shape:
    cubic
    Pure shape:
    no
    Range:
    > 5 - < 80 %
    Shape category:
    spheroidal
    Shape:
    spherical
    Pure shape:
    no
    Range:
    > 0 - < 30 %
    Shape category:
    elongated
    Shape:
    rod
    Pure shape:
    yes
    Range:
    > 5 - < 80 %

    Particle size distribution and range

    Particle size distribution and rangeopen allclose all
    Shape category:
    spheroidal
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.02 - <= 0.07 μm
    Percentile:
    D50
    Range:
    >= 0.035 - <= 0.115 μm
    Percentile:
    D90
    Range:
    >= 0.065 - <= 0.165 μm
    Additional information:
    the particle size distribution relates to both shape categories. The smallest dimension of all particles had been considered.
    Fraction of constituent particles in the size range 1-100 nm:
    >= 60 - <= 100 %
    Shape category:
    elongated
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.02 - <= 0.07 μm
    Percentile:
    D50
    Range:
    >= 0.035 - <= 0.115 μm
    Percentile:
    D90
    Range:
    >= 0.065 - <= 0.165 μm
    Range of length:
    >= 0.1 - <= 0.6 μm
    Range of aspect ratio (:1):
    >= 3 - <= 5.8
    Additional information:
    the particle size distribution relates to both shape categories. The smallest dimension of all particles had been considered.
    Fraction of constituent particles in the size range 1-100 nm:
    >= 60 - <= 100 %

    Crystallinity

    Structures
    Structure:
    crystalline
    Name:
    C.I. Pigment Orange 68
    Pure structure:
    yes

    Specific surface area

    Range of specific surface area:
    >= 10 - <= 50 m²/g
    Skeletal density:
    1.6 g/cm³

    Surface functionalisation / treatment

    Surface treatment applied:
    no
    State Form:
    solid: bulk


    Constituent 1
    Chemical structure
    Reference substance name:
    [1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
    EC Number:
    255-965-2
    EC Name:
    [1,3-dihydro-5,6-bis[[(2-hydroxy-1-naphthyl)methylene]amino]-2H-benzimidazol-2-onato(2-)-N5,N6,O5,O6]nickel
    CAS Number:
    42844-93-9
    Molecular formula:
    C29H18N4NiO3
    IUPAC Name:
    Nickel, [1,3-dihydro-5,6-bis[[[2-(hydroxy-kO)-1-naphthalenyl]methylene]amino-kN]-2H-benzimidazol-2-onato(2-)]-, (SP-4-2)-

    Composition(s) generated upon use

    Other types of composition(s)