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Guidance on Safe Use

First-aid measures

Description of first aid measures:

Pay attention to self-protection.

Remove victims from hazardous area.

Immediately remove soiled or soaked clothing and remove it to a safe distance.

Keep victim warm, in a stabilized position and covered.

Do not leave victims unattended.

If the casualty is unconscious: Place the victim in the recovery position.

Inhalation:

Potential for exposure by inhalation if aerosols or mists are generated.

Move victims into fresh air.

With labored breathing: Provide with oxygen. Consult a doctor.

If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.

Skin contact:

Wash off affected area immediately with plenty of water for at least 15 minutes.

If symptoms persist, consult a physician for treatment.

Eye contact:

With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.

Consult an ophthalmologist immediately if the symptoms persist.

Ingestion:

Rinse out mouth.

Immediately give large quantities of water to drink.

Consult a physician immediately.

Most important symptoms and effects, both acute and delayed:

Indication of any immediate medical attention and special treatment needed:

After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the noxious substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).

Continue with first aid measures.

Depending on the pathology and clinical findings, patient monitoring and symptomatic treatment are necessary.

Fire-fighting measures

Suitable extinguishing media:

Water spray, mist, carbon dioxide (CO2), dry powder

Unsuitable extinguishing media:

High volume water jet

Special hazards arising from the substance or mixture:

In the case of fire, the following hazardous smoke fumes may be produced:

Hydrogen chloride

Carbon monoxide

Special protective equipment for fire-fighters:

Wear suitable protective clothing.

Wear a self contained respiratory apparatus

Advice for firefighters:

Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure there are sufficient retaining facilities for water used to extinguish fire.

Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.

Fire residues should be disposed of in accordance with the regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Avoid contact with skin and eyes.

Keep away from sources of ignition - No smoking.

Do not inhale vapours / aerosols.

Wear personal protective equipment.

Environmental precautions:

Dike or contain spill.

Dam with sand or earth

To be disposed of in compliance with existing regulations.

Prevent product from entering drains.

Do not allow entrance in sewage water, soil or stretches of water.

Methods and material for containment and cleaning up:

Transfer into suitable containers.

Suitable binder: sand (for damming up), soda ash, universal absorbent.

Additional advice:

Remove all sources of ignition.

Ensure explosion proofness.

Observe regulations on prevention of water pollution.

Ensure there is sufficient ventilation.

Handling and storage

Handling:

Precautions for safe handling:

Use personal protective equipment.

Do not breathe in vapours, aerosols, sprays.

Advice on protection against fire and explosion:

Vapours can form explosive mixtures with air.

Keep away from sources of ignition - No smoking.

Explosion protection equipment required.

Storage:

Conditions for safe storage, including any incompatibilities:

Keep container tightly closed.

Protect from moisture.

Use shatterproof containers.

Explosion protection equipment required.

Unsuitable materials: copper, brass and their alloys, mild steel.

Further information:

Storage must be in accordance with the BetrSichV (Germany).

Secure container from falling down.

Advice on common storage:

Incompatible with strong acids and bases.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

1992

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, TOXIC, N.O.S.

Chemical name:

2-Chlor-1,1,1-trimethoxyethane

Language:

English

Labels:

3 (6.1)

Special provisions / remarks

Special provisions:

Tunnel Restriction Code (ADR)

Remarks:

(D/E)

Environmentally Hazardous

Inland waterway transport (UN RTDG/ADN(R))

UN number:

1992

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, TOXIC, N.O.S.

Chemical name:

2-Chlor-1,1,1-trimethoxyethane

Language:

English

Labels:

3 (6.1)

Special provisions / remarks

Remarks:

Environmentally Hazardous

Marine transport (UN RTDG/IMDG)

UN number:

1992

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, TOXIC, N.O.S.

Chemical name:

2-Chlor-1,1,1-trimethoxyethane

Labels:

3, 6.1

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

1992

Shipping information

Proper shipping name and description:

Flammable liquid, toxic, n.o.s.

Chemical name:

2-Chlor-1,1,1-trimethoxyethane

Labels:

3, 6.1

Special provisions / remarks

Remarks:

Environmentally Hazardous

IATA_C: ERG-Code 3P
IATA_P: ERG-Code 3P

Additional transport information

Additional information

Special provisions / remarks / other:

Loading instructions/Remarks:
Keep separate from foodstuffs, luxury foods, feedstuffs

Combination traffic :
Labelling of containers / shipping units following main product run as per sea or air transport regulations.

Exposure controls / personal protection

Engineering measures:

Provide sufficient air exchange and/or exhaust in work rooms.

If possible, use material transfer/filling, metering and blending plants that are closed, or provide for local suction devices.

Explosion protection equipment required.

Personal protective equipment:

Respiratory protection:

Use respiratory equipment with suitable filter (combined filter ABEK-P2) or wear a self contained respiratory apparatus.

Note time limit for wearing respiratory protective equipment.

Hand protection:

Glove material: Nitrile, for example:, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany

Material thickness 0.11 mm

Method DIN EN 374

Accidental release measures:

Glove material Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany

Material thickness 0.65 mm

Method DIN EN 374

Eye protection:

Close-fitting protective goggles (e.g. closed goggles) recommended.

Safety glasses with side-shields conforming to EN166.

Skin and body protection:

Suitable protective clothing.

Use disposable clothing if appropriate.

Hygiene measures:

Do not breathe vapours.

Avoid contact with skin and eyes.

Wash off immediately in the event of contact with the skin (rinsing agent: glycol polyethylene 400), rinse off afterwards with copious amounts of water.

No eating, drinking, smoking, or snuffing tobacco at work.

Wash face and/or hands before break and end of work.

Take off clothing and shoes contaminated with product.

Clean before reuse.

Recommendation: Keep clothes separate.

Protective measures:

The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).

Stability and reactivity

Conditions to avoid:

Avoid temperatures above 40 °C.

Hazardous decomposition products:

Decomposition products from hydrolysis in water:

Methanol

Disposal considerations

Product:

The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.

Uncleaned packaging:

With respect to local regulations, e.g. dispose of to suitable waste incineration plant.