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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Phototransformation in soil

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
phototransformation in soil
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Qualifier:
according to guideline
Guideline:
EPA Guideline Subdivision N 161-3 (Photodegradation Studies on Soil)
Deviations:
no
GLP compliance:
no
Specific details on test material used for the study:
- Substance name: [1-14C]Methomyl
- Lot #: 1800-056
- Purity: Not reported
Radiolabelling:
yes
Analytical monitoring:
yes
Analytical method:
high-performance liquid chromatography
other: LSC, TLC
Light source:
sunlight
Duration:
30 d
Temp.:
28 °C
Initial conc. measured:
1 other: lb/a.i. acre
Reference substance:
yes
Dark controls:
yes
Key result
DT50:
34 d
Test condition:
test substance in soil exposed to natural sunlight
Transformation products:
yes
Remarks:
Acetonitrile
Conclusions:
The test substance decomposed with a half-life of 34 days to form acetonitrile, the only detected radioactive decomposition product
Executive summary:

The study was conducted according to EPA Guideline 161-3. Radiolabeled [1-14C]test substance was applied evenly (at a rate equivalent to 1 lb/a.i. acre) to a thin layer of keyport silt loam and exposed to natural sunlight for 30 days at a temperature of 24-28°C. Under these conditions, the test substance decomposed with a half-life of 34 days to form acetonitrile, the only detected radioactive decomposition product. Controls kept in the dark did not decompose.

Description of key information

Study Type

 Study Details Value  Guideline Reliability 
Phototransformation in soil

Applied evenly to keyport silt loam and exposed to natural sunlight

DT50 = 34 days

Decomposition product was acetonitrile

EPA 161-3

Key value for chemical safety assessment

Half-life in soil:
34 d

Additional information