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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2012-03-16 - 2012-03-20
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Parameter:
sensitiveness to friction: friction load (N)
Remarks on result:
not sensitive to friction using a friction load of 360 N
Key result
Parameter:
sensitiveness to impact: impact energy (J)
Remarks on result:
not sensitive to impact using an impact energy of 40 J
Key result
Parameter:
thermal sensitivity - Koenen test: diameter of the orifice plate
Remarks on result:
not thermal sensitive if heated under defined confinement

Friction test

Six negative assays were recorded: No friction sensitivity was noted with the test item with a loading of 360 Newtons. No further tests were performed.

Mechanical sensitivity (shock)

Six negative assays were recorded: No shock sensitivity was noted with the 40-J force.

No further tests were performed.

Heat sensitivity (flame)

Three assays using a tube with a hole of 6-mm diameter: between approx 2 and 3.5 min, the test item overflowed and a 20-cm height orange flame was observed (in 2 assays). The 20 -cm height orange flame in the 2 assays was observed until the end of the observation time (5 min).

Three assays using a tube with a hole of 2-mm diameter: between approx 2 and 2.5 min, the test item overflowed.

In conclusion: six negative assays were recorded: No heat sensitivity was noted with the test item.

Interpretation of results:
non explosive
Conclusions:
Praseodymium trinitrate was concluded not to be explosive when exposed to friction, shock or heat.

Description of key information

Following a GLP study in accordance with EC test method A.14, praseodymium trinitrate is concluded not to be explosive (Ferron, 2012).

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

The experimental data show that praseodymium trinitrate is not sensitive to friction, shock or heat.

Justification for classification or non-classification

Based on a GLP study performed in accordance with EC test method A.14, praseodymium trinitrate was concluded not to have explosive properties. This results in an absence of classification under both DSD and CLP systems.