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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Identification

Display Name:
Alkaline co-precipitation products of soluble aluminium, cobalt and nickel salts
Molecular formula:
not applicable, UVCB
IUPAC Name:
Alkaline co-precipitation products of soluble aluminium, cobalt and nickel salts

Type of Substance

Composition:
UVCB
Origin:
inorganic

Substance Identifiers

Compositions

Boundary Composition(s) open all close all

State Form:
solid: nanoform


Constituent 1
Chemical structure
Reference substance name:
Nickel dihydroxide
EC Number:
235-008-5
EC Name:
Nickel dihydroxide
CAS Number:
12054-48-7
Molecular formula:
H2NiO2
IUPAC Name:
nickel(2+) dihydroxide
Constituent 2
Chemical structure
Reference substance name:
Cobalt dihydroxide
EC Number:
244-166-4
EC Name:
Cobalt dihydroxide
CAS Number:
21041-93-0
Molecular formula:
CoH2O2
IUPAC Name:
cobalt(2+) dihydroxide
Constituent 3
Chemical structure
Reference substance name:
Tricobalt tetraoxide
EC Number:
215-157-2
EC Name:
Tricobalt tetraoxide
CAS Number:
1308-06-1
Molecular formula:
Co3O4
IUPAC Name:
tricobalt tetraoxide
Constituent 4
Chemical structure
Reference substance name:
Aluminium hydroxide
EC Number:
244-492-7
EC Name:
Aluminium hydroxide
CAS Number:
21645-51-2
Molecular formula:
AlH3O3
IUPAC Name:
aluminum trihydroxide
Constituent 5
Chemical structure
Reference substance name:
Sodium sulphate
EC Number:
231-820-9
EC Name:
Sodium sulphate
CAS Number:
7757-82-6
Molecular formula:
H2O4S.2Na
IUPAC Name:
disodium sulfate
Constituent 6
Chemical structure
Reference substance name:
Water
EC Number:
231-791-2
EC Name:
Water
CAS Number:
7732-18-5
Molecular formula:
H2O
IUPAC Name:
water

Characterisation of nanoforms

Type of information reported:
single nanoform
Name of nanoform:
Alkaline co-precipitation products of soluble aluminium, cobalt and nickel salts

Shape

Shape description
Shape category:
platelet
Shape:
plate
Pure shape:
yes
Typical composition:
ca. 100 %
Range:
>= 80 - <= 100 %

Particle size distribution and range

Particle size distribution and range
Shape category:
platelet
Percentileopen allclose all
Percentile:
D10
Typical value:
ca. 15 nm
Range:
>= 10 - <= 30 nm
Percentile:
D50
Typical value:
ca. 20 nm
Range:
>= 10 - <= 30 nm
Percentile:
D90
Typical value:
ca. 25 nm
Range:
>= 15 - <= 40 nm
Typical lateral dimension 1:
ca. 120 nm
Range of lateral dimension 1:
>= 40 - <= 250 nm
Typical lateral dimension 2:
ca. 120 nm
Range of lateral dimension 2:
>= 40 - <= 250 nm
Typical aspect ratio (:1):
ca. 5.6 :1
Range of aspect ratio (:1):
>= 5 - <= 6
Fraction of constituent particles in the size range 1-100 nm:
>= 99.9 - <= 100 %

Crystallinity

Structuresopen allclose all
Structure:
partially-crystalline
Name:
crystalline
Pure structure:
no
Typical composition:
ca. 50 %
Range:
>= 10 - <= 90 %
Crystal system:
trigonal
Structure:
partially-crystalline
Name:
amorphous
Pure structure:
no
Typical composition:
ca. 50 %
Range:
>= 10 - <= 90 %
Crystal system:
not applicable
Description:
Further information regarding crystallinity can be found in the expert statement in section 1.4. of the IUCLID dossier.

Specific surface area

Typical specific surface area:
ca. 43.5 m²/g
Range of specific surface area:
>= 40 - <= 50 m²/g
Typical volume specific surface area:
ca. 156.6
Range of volume specific surface area:
>= 150 - <= 165 m²/cm³
Skeletal density:
ca. 3.6 g/cm³

Surface functionalisation / treatment

Surface treatment applied:
no

Legal Entity Composition(s) open all close all

State Form:
solid: nanoform


Constituent 1
Chemical structure
Reference substance name:
Nickel dihydroxide
EC Number:
235-008-5
EC Name:
Nickel dihydroxide
CAS Number:
12054-48-7
Molecular formula:
H2NiO2
IUPAC Name:
nickel(2+) dihydroxide
Constituent 2
Chemical structure
Reference substance name:
Cobalt dihydroxide
EC Number:
244-166-4
EC Name:
Cobalt dihydroxide
CAS Number:
21041-93-0
Molecular formula:
CoH2O2
IUPAC Name:
cobalt(2+) dihydroxide
Constituent 3
Chemical structure
Reference substance name:
Tricobalt tetraoxide
EC Number:
215-157-2
EC Name:
Tricobalt tetraoxide
CAS Number:
1308-06-1
Molecular formula:
Co3O4
IUPAC Name:
tricobalt tetraoxide
Constituent 4
Chemical structure
Reference substance name:
Aluminium hydroxide
EC Number:
244-492-7
EC Name:
Aluminium hydroxide
CAS Number:
21645-51-2
Molecular formula:
AlH3O3
IUPAC Name:
aluminum trihydroxide
Constituent 5
Chemical structure
Reference substance name:
Sodium sulphate
EC Number:
231-820-9
EC Name:
Sodium sulphate
CAS Number:
7757-82-6
Molecular formula:
H2O4S.2Na
IUPAC Name:
disodium sulfate
Constituent 6
Chemical structure
Reference substance name:
Water
EC Number:
231-791-2
EC Name:
Water
CAS Number:
7732-18-5
Molecular formula:
H2O
IUPAC Name:
water

Characterisation of nanoforms

Type of information reported:
single nanoform
Name of nanoform:
Alkaline co-precipitation products of soluble aluminium, cobalt and nickel salts

Shape

Shape description
Shape category:
platelet
Shape:
plate
Pure shape:
yes
Typical composition:
ca. 100 %
Range:
>= 80 - <= 100 %

Particle size distribution and range

Particle size distribution and range
Shape category:
platelet
Percentileopen allclose all
Percentile:
D10
Typical value:
ca. 15 nm
Range:
>= 10 - <= 30 nm
Percentile:
D50
Typical value:
ca. 20 nm
Range:
>= 10 - <= 30 nm
Percentile:
D90
Typical value:
ca. 25 nm
Range:
>= 15 - <= 40 nm
Typical lateral dimension 1:
ca. 120 nm
Range of lateral dimension 1:
>= 40 - <= 250 nm
Typical lateral dimension 2:
ca. 120 nm
Range of lateral dimension 2:
>= 40 - <= 250 nm
Typical aspect ratio (:1):
ca. 5.6 :1
Range of aspect ratio (:1):
>= 5 - <= 6
Fraction of constituent particles in the size range 1-100 nm:
>= 99.9 - <= 100 %

Crystallinity

Structuresopen allclose all
Structure:
partially-crystalline
Name:
crystalline
Pure structure:
no
Typical composition:
ca. 50 %
Range:
>= 10 - <= 90 %
Crystal system:
trigonal
Structure:
partially-crystalline
Name:
amorphous
Pure structure:
no
Typical composition:
ca. 50 %
Range:
>= 10 - <= 90 %
Crystal system:
not applicable
Description:
The particles are partially crystalline.
The dominant phase of the cathode active material precursor is Me(OH)2 with Me= Ni, Co, Al in the corresponding ratio.
a= 0.3126(81)
b= 0.3126(81)
c= 0.4606(01)
symmetry (space-group): P -3 m 1 (164)

Further information regarding crystallinity can be found in the expert statement in section 1.4.

Specific surface area

Typical specific surface area:
ca. 43.5 m²/g
Range of specific surface area:
>= 20 - <= 60 m²/g
Typical volume specific surface area:
ca. 157 m²/cm³
Range of volume specific surface area:
>= 140 - <= 200 m²/cm³
Skeletal density:
ca. 3.6

Surface functionalisation / treatment

Surface treatment applied:
no
State Form:
solid: nanoform


Constituent 1
Chemical structure
Reference substance name:
Nickel dihydroxide
EC Number:
235-008-5
EC Name:
Nickel dihydroxide
CAS Number:
12054-48-7
Molecular formula:
H2NiO2
IUPAC Name:
nickel(2+) dihydroxide
Constituent 2
Chemical structure
Reference substance name:
Cobalt dihydroxide
EC Number:
244-166-4
EC Name:
Cobalt dihydroxide
CAS Number:
21041-93-0
Molecular formula:
CoH2O2
IUPAC Name:
cobalt(2+) dihydroxide
Constituent 3
Chemical structure
Reference substance name:
Tricobalt tetraoxide
EC Number:
215-157-2
EC Name:
Tricobalt tetraoxide
CAS Number:
1308-06-1
Molecular formula:
Co3O4
IUPAC Name:
tricobalt tetraoxide
Constituent 4
Chemical structure
Reference substance name:
Aluminium hydroxide
EC Number:
244-492-7
EC Name:
Aluminium hydroxide
CAS Number:
21645-51-2
Molecular formula:
AlH3O3
IUPAC Name:
aluminum trihydroxide
Constituent 5
Chemical structure
Reference substance name:
Sodium sulphate
EC Number:
231-820-9
EC Name:
Sodium sulphate
CAS Number:
7757-82-6
Molecular formula:
H2O4S.2Na
IUPAC Name:
disodium sulfate
Constituent 6
Chemical structure
Reference substance name:
Water
EC Number:
231-791-2
EC Name:
Water
CAS Number:
7732-18-5
Molecular formula:
H2O
IUPAC Name:
water

Characterisation of nanoforms

Type of information reported:
single nanoform
Name of nanoform:
Alkaline co-precipitation products of soluble aluminium, cobalt and nickel salts

Shape

Shape description
Shape category:
platelet
Shape:
plate
Pure shape:
yes
Typical composition:
ca. 100 %
Range:
>= 80 - <= 100 %

Particle size distribution and range

Particle size distribution and range
Shape category:
platelet
Percentileopen allclose all
Percentile:
D10
Typical value:
ca. 15 nm
Range:
>= 10 - <= 30 nm
Percentile:
D50
Typical value:
ca. 20 nm
Range:
>= 10 - <= 30 nm
Percentile:
D90
Typical value:
ca. 25 nm
Range:
>= 15 - <= 40 nm
Typical lateral dimension 1:
ca. 120 nm
Range of lateral dimension 1:
>= 40 - <= 120 nm
Typical lateral dimension 2:
ca. 120 nm
Range of lateral dimension 2:
>= 40 - <= 120 nm
Typical aspect ratio (:1):
ca. 5.6 :1
Range of aspect ratio (:1):
>= 5 - <= 6
Fraction of constituent particles in the size range 1-100 nm:
>= 99.9 - <= 100 %

Crystallinity

Structuresopen allclose all
Structure:
partially-crystalline
Name:
crystalline
Pure structure:
no
Typical composition:
ca. 50 %
Range:
>= 10 - <= 90 %
Crystal system:
trigonal
Structure:
partially-crystalline
Name:
amorphous
Pure structure:
no
Typical composition:
ca. 50 %
Range:
>= 10 - <= 90 %
Crystal system:
not applicable
Description:
The particles are partially crystalline.
The dominant phase of the cathode active material precursor is Me(OH)2 with Me= Ni, Co, Al in the corresponding ratio.
a= 0.3126(81)
b= 0.3126(81)
c= 0.4606(01)
symmetry (space-group): P -3 m 1 (164)

Further information regarding crystallinity can be found in the expert statement in section 1.4.

Specific surface area

Typical specific surface area:
ca. 43.5 m²/g
Range of specific surface area:
>= 20 - <= 60 m²/g
Typical volume specific surface area:
ca. 157 m²/cm³
Range of volume specific surface area:
>= 140 - <= 200 m²/cm³
Skeletal density:
ca. 3.6

Surface functionalisation / treatment

Surface treatment applied:
no

Composition(s) generated upon use

Other types of composition(s)