Registration Dossier

Administrative data

First-aid measures

· General information:
Immediately remove any clothing soiled by the product.
Take note of the following instructions:
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in the recovery position for transportation.
· After skin contact:
If skin irritation occurs, consult a doctor.
Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
Seek medical treatment.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
Rinse out mouth and then drink plenty of water.
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

· Suitable extinguishing agents:
Special powder for metal fires. Do not use water.
Cement
Dry sand
· For safety reasons unsuitable extinguishing agents: Water
· Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Toxic metal oxide smoke
· Protective equipment: Wear self-contained respiratory protective device.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear personal protective equipment. Keep unprotected persons away.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Sweep the spill area; avoid raising dust.
Dispose of the material collected according to regulations.
Dispose contaminated material as waste according to 'Disposal considerations'
Ensure adequate ventilation.
· Reference to other sections
In case of fire, nickel oxide, classified as carcinogenic, can be produced.

Handling and storage

· Precautions for safe handling
Avoid formation of respirable particles.
Extractor required at the object.
Work only in fume cupboard.
Prevent formation of dust.
Open and handle receptacle with care.
· Information about fire - and explosion protection:
Keep respiratory protective device available.
Product dust together with air may develop ignitable and explosive mixtures.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Traces of flammable substances may collect in the steam chamber of enclosed systems. Keep
clear ofignition sources.
· Conditions for safe storage, including any incompatibilities
· Storage: Store in a cool location.
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility:
Do not store together with alkalis (caustic solutions).
Store away from water.
Store away from foodstuffs.
Store away from oxidising agents.
· Further information about storage conditions:
Store under lock and key and with access restricted to technical experts or their assistants only.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· Specific end use(s) No further relevant information available.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
NONE
Shipping information
Proper shipping name and description:
NONE
Chemical name:
aluminum, compound with nickel (1:1)
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
NONE
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Marine transport (UN RTDG/IMDG)

UN number:
NONE
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Air transport (UN RTDG/ICAO/IATA)

UN number:
NONE
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Special provisions / remarks
Remarks:
GRACE recommends CARGO AIRCRAFT only.
GRACE requires Transport Packaging certified for Packaging Group III according to 6.1 (ADR/IMDG), §173.203 (DOT), and/or 5.0.2 (IATA).
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Exposure controls / personal protection

Additional information about design of technical facilities: No further data; see 'Handling and Storage · Ingredients with limit values that require monitoring at the workplace:
12003-78-0 aluminum, compound with nickel (1:1)
WEL (Great Britain) Long-term value: 0.5 mg/m³ as Ni
· Additional Occupational Exposure Limit Values for possible hazards during processing:
Nickel and its inorganic compounds (except nickel tetracarbonyl): nickel and waterinsoluble
WEL (Great Britain) Long-term value: 0.1 mg/m³
Sk Carc (Ni oxide & sulphides), Sen (Ni sulpate)

Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
· Respiratory protection:
If the WEL value is exceeded.
Filter P3
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Protection of hands:
Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.
Use gloves of stable material (e.g. Nitrile) - if necessary tricoted to improve the wearability.
Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
Butyl rubber, BR
Nitrile rubber, NBR
EN 388: Minimum requirements for efficiency level 1 for all groups.
Recommended thickness of the material: ≥ 0.35 mm
The selection of the suitable gloves does not only depend on the material, but also on further
marks of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
· Eye protection: Tightly sealed goggles
· Body protection: Protective work clothing.

Stability and reactivity

Reactivity No further relevant information available.
· Chemical stability To avoid thermal decomposition do not overheat.
· Possibility of hazardous reactions
Product dust together with air may develop ignitable and explosive mixtures.
Risk of dust explosion.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
· Incompatible materials:
Protect from contamination.
Decomposes with water, acids and alkalis.
· Hazardous decomposition products: Toxic metal oxide smoke

Disposal considerations

Waste treatment methods
· Recommendation: Disposal must be made according to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste producer.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.