Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

General information : Get medical aid.
First aid measures :
- Inhalation : Assure fresh air breathing. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
- Skin contact : Wash skin thoroughly with mild soap and water. Immediately transport the victim to the hospital.
- Eye contact : Rinse immediately with plenty of water for at least 15 min. Occasionally lift up the upper and lower eyelids.
- Ingestion : If swallowed, rinse mouth with water (only if the person is conscious).

Fire-fighting measures

Extinguishing media : Alcohol-resistant foam, dry powder, carbon dioxide, water spray.
Special hazrads arising from the substance: nitrogen oxides, hydrogen bromide gas, dioxide oxides.
Protection against fire : If necessary, use an autonomous respiratory protection for the fire control.

Accidental release measures

Personal precautions : Use proper personal protective equipment as indicated in Section Exposure controls and personal precaution. Avoid generating dusty conditions. Avoid inhalation. Ensure adequate ventilation. Evacuate personnel to safe places.
Environmental precautions : Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Clean up methods : Collect and evacuate without creating dust. Keep in suitable and closed containers for disposal.

Handling and storage

Storage : Store in tightly closed containers. Store in dry, cool, well-ventilated area.
Handling : Avoid any contact with skin and eyes. Avoid formation of dust and aerosols. Provide adequate ventilation where dust is formed. Normal measures for preventive fire protection.
This substance is handled under strictly controlled conditions in accordance with Reach regulation Article 18(4) for transported isolated intermediate. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each site. Written confirmation of application of strictly controlled conditions has been received from every downstream user of the intermediate.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2811
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Labels:
6,1
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
2811
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Labels:
6,1
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Marine transport (UN RTDG/IMDG)

UN number:
2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S.
Chemical name:
4-Bromo-1,2-diaminobenzene
Labels:
6,1
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Air transport (UN RTDG/ICAO/IATA)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
4-Bromo-1,2-diaminobenzene
Labels:
6,1
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Exposure controls / personal protection

Industrial hygiene : Use adequate ventilation to keep airbone concentrations low . Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
Personal protection :
- Respiratory protection : When risk assessment shows that the use of breathing apparatus is appropriate, use a dust mask type N99 (US) or type P2 (EN 143). If the mask is the only protection, use a self-contained breathing apparatus with full face shield. Use equipment and components tested and approved by NIOSH (US) and CEN (EU).
- Hand protection : Manipulate with gloves. Gloves have to be controlled before the use. Use a technique of withdrawal suited to avoid that the skin contacts the product (i.e. without touching the outside of the glove). Throw contamnated gloves after the use according to the current laws and to the good practices of laboratory. Wash and dry hands. The selected gloves have to satisfy the specifications of the EU Directive 89/686/EEC and in the standard IN 374 which derives from it.
- Skin protection : Combination of protection against chemicals. The type of equipment of protection must be selected according to the concentration and to the quantity of the dangerous substance at work.
- Eye protection : Facial protection and safety goggles. Use an equipment of protection of eyes tested and approved according to the current governmental standards, such as NIOSH (US) or IN 166 (EU).

This substance is handled under strictly controlled conditions in accordance with Reach regulation Article 18(4) for transported isolated intermediate. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each site. Written confirmation of application of strictly controlled conditions has been received from every downstream user of the intermediate.

Stability and reactivity

Materials to avoid : strong oxidizing agents.
Conditions to avoid : incompatible materials.

Disposal considerations

Dispose in a safe manner in accordance with local / national regulations.