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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
hydrolysis
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
comparable to guideline study

Data source

Reference
Reference Type:
other: Registration Dossoer
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method C.7 (Degradation: Abiotic Degradation: Hydrolysis as a Function of pH)
Version / remarks:
Due to the physical-chemical properties of the test item it is impossible to investigate its hydrolytic propertiesaccording to the EU Commision Regulation (EC) No. 440/2008C.7. According to literature, in auqeous solution stannic chloride is cleaved by hydrlysis
Deviations:
yes
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Tin tetrachloride
EC Number:
231-588-9
EC Name:
Tin tetrachloride
Cas Number:
7646-78-8
Molecular formula:
Cl4Sn
IUPAC Name:
tin tetrachloride
Radiolabelling:
no

Study design

Analytical monitoring:
yes
Positive controls:
no
Negative controls:
no

Results and discussion

Preliminary study:
Preliminary study:
Because of the difficult handling and high instability of the test item the performance of the hydrolysis test described in the European Commission Regulation (EC)440/2008 C.7 and in the OECD guideline 111 was modified. Nevertheless the observation made during the performance of the test and the calculations showed that in distilled water 90 -96 % of the test item was hydrolized after a time period of 2.5 h. Therefore the tested substance has to be considered as hydrolytically unstable and according to the guidelines no additional testing is required.
Transformation products:
yes
Identity of transformation productsopen allclose all
No.:
#1
Reference
Reference substance name:
Unnamed
IUPAC name:
chloride
Inventory number:
InventoryMultipleMappingImpl [inventoryEntryValue=EC 231-595-7]
CAS number:
7647-01-0
Identity:
Hydrochloric acid
Molecular formula:
ClH
Molecular weight:
35.453
SMILES notation:
[Cl-]
InChl:
InChI=1/ClH/h1H/p-1
No.:
#2
Reference
Reference substance name:
Unnamed
Inventory number:
InventoryMultipleMappingImpl [inventoryEntryValue=EC 242-159-0]
CAS number:
18282-10-5
Molecular formula:
O2Sn
Total recovery of test substance (in %)
Remarks on result:
not determinable because of methodological limitations
Dissipation DT50 of parent compound
Remarks on result:
not determinable because of methodological limitations
Remarks:
reaction to fast

Applicant's summary and conclusion

Validity criteria fulfilled:
yes
Conclusions:
tin tetrachloride hydrolyses at once in contact with humidity or water in hydrogen chloride and tin dioxide