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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Endpoint summary

Administrative data

Description of key information

Additional information

The registration substance is a multi-constituent substance containing four constituents, decamethyltetrasiloxane (L4, CAS 141-62-8), dodecamethylpentasiloxane (L5, CAS 141-63-9), hexamethyldisiloxane (HMDS, CAS 107-46-0) and octamethyltrisiloxane (L3, CAS 107-51-7).

The properties of the substance as a whole are relevant in the context of safe handling and use. In the environment, the individual constituents may behave independently of each other, and therefore for the purposes of assessing environmental fate and behaviour, the properties of the constituents are relevant. Therefore, both whole substance data (where available) and individual constituent data are reported.

The registration substance is a liquid at standard temperature and pressure, with a melting point of <-100.0°C and a boiling point of 159.2°C. It has a measured relative density of 0.8306 at 20°C and a measured vapour pressure of 390 Pa at 20°C. The substance is classified as Flammable Liquid Category 3 (H226: flammable liquid and vapour) according to Regulation (EC) No 1272/2008. This is on the basis of a measured flash point of 29.0°C and a measured boiling point of 159.2°C. It has a measured autoignition temperature of 345°C at 964 hPa and is not explosive and not oxidising on the basis of chemical structure.

The key physico-chemical properties of the constituents are presented in the table below:

Table: Key physicochemical properties of constituents of the substance

Property

HMDS (107-46-0)

L3 (107 -51-7)

L4 (141-62-8)

L5 (141-63-9)

Molecular weight

162.38

236.54

310.69

348.9

Log Kow

5.06

6.60

8.21

9.3-9.5

Water solubility (mg/l)

0.93 (at 23°C)

3.4E-02 (at 23°C)

6.7E-03 mg/l at 23°C

7.0E-05 mg/l at 23°C

Vapour pressure at 25°C (Pa)

5500

530

73

7.8

Hydrolysis half- life at pH 7 (h) and 25°C

116

329

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