Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 229-745-1 | CAS number: 6701-13-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General advice:
Show this safety data sheet to the doctor in attendance.
Inhalation:
Move to fresh air. In case of problems : Consult a doctor
Skin contact:
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. In the case of skin irritation or allergic
reactions see a physician.
Eye contact:
Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Seek advice of an ophthalmologist if necessary.
Ingestion:
Do NOT induce vomiting. Rinse mouth. Consult a physician if necessary
Show this safety data sheet to the doctor in attendance.
Inhalation:
Move to fresh air. In case of problems : Consult a doctor
Skin contact:
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. In the case of skin irritation or allergic
reactions see a physician.
Eye contact:
Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Seek advice of an ophthalmologist if necessary.
Ingestion:
Do NOT induce vomiting. Rinse mouth. Consult a physician if necessary
Fire-fighting measures
Suitable extinguishing media: Carbon dioxide (CO2), foam, Dry chemical
Unsuitable extinguishing media: High volume water jet
Special hazards arising from the substance or mixture:
Formation of toxic products through combustion:, Carbon oxides
Advice for firefighters:Specific methods:
In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Do not allow run-off from fire fighting
to enter drains or water courses.
Special protective actions for fire-fighters:
In the event of fire, wear self-contained breathing apparatus and protective suit.
Unsuitable extinguishing media: High volume water jet
Special hazards arising from the substance or mixture:
Formation of toxic products through combustion:, Carbon oxides
Advice for firefighters:Specific methods:
In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Do not allow run-off from fire fighting
to enter drains or water courses.
Special protective actions for fire-fighters:
In the event of fire, wear self-contained breathing apparatus and protective suit.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. Prohibit
contact with skin and eyes.
Environmental precautions: Do not flush into surface water or sanitary sewer system. Do not release into the environment.
Methods and materials for containment and cleaning up:
Recovery:
Shovel into suitable container for disposal. Absorb the remainder with an inert absorbent material (sand, vermiculite, perlite). No sparking
tools should be used.
Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. Prohibit
contact with skin and eyes.
Environmental precautions: Do not flush into surface water or sanitary sewer system. Do not release into the environment.
Methods and materials for containment and cleaning up:
Recovery:
Shovel into suitable container for disposal. Absorb the remainder with an inert absorbent material (sand, vermiculite, perlite). No sparking
tools should be used.
Handling and storage
Precautions for safe handling:
Technical measures/Precautions:
Storage and handling precautions applicable to products: Solid. Irritant. Sensitizing. Provide appropriate exhaust ventilation at machinery.
Provide showers, eye-baths
Safe handling advice:
Remove all sources of ignition. Avoid static electricity build up with connection to earth. In case of insufficient ventilation, wear suitable
respiratory equipment
Hygiene measures:
Prohibit contact with skin and eyes. When using do not eat, drink or smoke. Avoid breathing dust.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities:
Keep tightly closed in a dry, cool and well-ventilated place. Store in original container. Protect from frost, heat and sunlight. Keep away from
open flames, hot surfaces and sources of ignition. Make sure of the presence of air and inhibitor in the drums.
Storage period: 6 Months, Storage temperature: < 45 °C
Incompatible products:
Acids, Bases, Oxidizing agents, Reducing agents
Packaging material:
Recommended: Baked phenolic lined carbon steel drums, Plastic drum
To be avoided: copper, Iron
Technical measures/Precautions:
Storage and handling precautions applicable to products: Solid. Irritant. Sensitizing. Provide appropriate exhaust ventilation at machinery.
Provide showers, eye-baths
Safe handling advice:
Remove all sources of ignition. Avoid static electricity build up with connection to earth. In case of insufficient ventilation, wear suitable
respiratory equipment
Hygiene measures:
Prohibit contact with skin and eyes. When using do not eat, drink or smoke. Avoid breathing dust.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities:
Keep tightly closed in a dry, cool and well-ventilated place. Store in original container. Protect from frost, heat and sunlight. Keep away from
open flames, hot surfaces and sources of ignition. Make sure of the presence of air and inhibitor in the drums.
Storage period: 6 Months, Storage temperature: < 45 °C
Incompatible products:
Acids, Bases, Oxidizing agents, Reducing agents
Packaging material:
Recommended: Baked phenolic lined carbon steel drums, Plastic drum
To be avoided: copper, Iron
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
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Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters:
Exposure Limit Values (dust)
Source Date Value type Value
(ppm)
Value
(mg/m3)
Remarks
ACGIH (US) 2008 TWA – 10 Inhalable particles.
ACGIH (US) 2008 TWA – 3 Respirable particles.
Exposure controls:
Appropriate engineering controls: When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air
suitable for breathing and wear the recommended equipment.
Personal protective equipment:
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment
Hand protection: Gloves nitrile rubber
Products used with solvents Do not use:, Natural Rubber, Gloves should be discarded and
replaced if there is any indication of degradation or chemical breakthrough.
Eye/face protection: Safety glasses with side-shields, Do not wear contact lenses.
Skin and body protection: Long sleeved clothing
Exposure Limit Values (dust)
Source Date Value type Value
(ppm)
Value
(mg/m3)
Remarks
ACGIH (US) 2008 TWA – 10 Inhalable particles.
ACGIH (US) 2008 TWA – 3 Respirable particles.
Exposure controls:
Appropriate engineering controls: When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air
suitable for breathing and wear the recommended equipment.
Personal protective equipment:
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment
Hand protection: Gloves nitrile rubber
Products used with solvents Do not use:, Natural Rubber, Gloves should be discarded and
replaced if there is any indication of degradation or chemical breakthrough.
Eye/face protection: Safety glasses with side-shields, Do not wear contact lenses.
Skin and body protection: Long sleeved clothing
Stability and reactivity
Reactivity & Chemical stability: The product is stable under normal handling and storage conditions.
Possibility of hazardous reactions: Inhibitors have been added to stabilize this product Maintaining air in the storage containers is important to keep inhibitors active
Conditions to avoid: Heat, flames and sparks. Remove all sources of ignition. Take precautionary measures against static discharges.
Incompatible materials to avoid: Acids, Bases, Oxidizing agents, Reducing agents
Hazardous decomposition products: Formation of toxic products through combustion:, Carbon oxides
Possibility of hazardous reactions: Inhibitors have been added to stabilize this product Maintaining air in the storage containers is important to keep inhibitors active
Conditions to avoid: Heat, flames and sparks. Remove all sources of ignition. Take precautionary measures against static discharges.
Incompatible materials to avoid: Acids, Bases, Oxidizing agents, Reducing agents
Hazardous decomposition products: Formation of toxic products through combustion:, Carbon oxides
Disposal considerations
Disposal of product: Do not release into the environment. Dispose of in accordance with local regulations.
Disposal of packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal.
Local provisions: In accordance with local and national regulations. : According to the European Waste Catalogue,
Waste Codes are not product specific, but application specific. , Waste codes should be assigned by
the user based on the application for which the product was used.
Disposal of packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal.
Local provisions: In accordance with local and national regulations. : According to the European Waste Catalogue,
Waste Codes are not product specific, but application specific. , Waste codes should be assigned by
the user based on the application for which the product was used.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
