Registration Dossier
Registration Dossier
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EC number: 931-227-1 | CAS number: 28497-59-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
General advice: First aider needs to protect himself.Take off all contaminated clothing immediately.Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.
Inhalation: Move subject to fresh air and keep him calm. See a physician.
Skin contact: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before re-use.
Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Consult a physician.
Ingestion: Do not induce vomiting and seek medical advice immediately. Never give anything by mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayed
Eye irritation
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
General advice: First aider needs to protect himself.Take off all contaminated clothing immediately.Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.
Inhalation: Move subject to fresh air and keep him calm. See a physician.
Skin contact: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before re-use.
Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Consult a physician.
Ingestion: Do not induce vomiting and seek medical advice immediately. Never give anything by mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayed
Eye irritation
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
foam
dry chemical
carbon dioxide
Unsuitable extinguishing media:
High volume water jet
5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.
Keep out unprotected persons.
Containers exposed to heat (fire) may build up pressure. Cool by splashing with water.
Closed container may rupture if strongly heated.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Suitable extinguishing media:
foam
dry chemical
carbon dioxide
Unsuitable extinguishing media:
High volume water jet
5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.
Keep out unprotected persons.
Containers exposed to heat (fire) may build up pressure. Cool by splashing with water.
Closed container may rupture if strongly heated.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep people away from and upwind of spill/leak.
Leave room immediately.
Immediately evacuate personnel to safe areas.
Ensure sufficient ventilation. Use personal protective equipment.
Use breathing apparatus if exposed to vapours/dust/mist/aerosol.
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.
Wash hands thoroughly with soap and water after handling.
Take precautionary measures against static discharges.
Keep away from open flames, hot surfaces and sources of ignition.
Vapours can form explosive mixtures with air.
6.2. Environmental precautions
Prevent product from getting into drains/surface water/groundwater.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3. Methods and material for containment and cleaning up
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment!
Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust).
Dispose of in accordance with regulations.
6.4. Reference to other sections
For personal protection see section 8.
For waste treatment see section 13.
Keep people away from and upwind of spill/leak.
Leave room immediately.
Immediately evacuate personnel to safe areas.
Ensure sufficient ventilation. Use personal protective equipment.
Use breathing apparatus if exposed to vapours/dust/mist/aerosol.
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.
Wash hands thoroughly with soap and water after handling.
Take precautionary measures against static discharges.
Keep away from open flames, hot surfaces and sources of ignition.
Vapours can form explosive mixtures with air.
6.2. Environmental precautions
Prevent product from getting into drains/surface water/groundwater.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3. Methods and material for containment and cleaning up
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment!
Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust).
Dispose of in accordance with regulations.
6.4. Reference to other sections
For personal protection see section 8.
For waste treatment see section 13.
Handling and storage
7.1. Precautions for safe handling
Safe handling advice: Provide sufficient ventilation and exhaust at the workplace. Provide good room ventilation even at ground level (vapours are heavier than air). Keep container tightly closed. No eating, drinking, smoking, or snuffing tobacco at work. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Wash thoroughly after handling. Follow all SDS/label precautions even after container is emptied because it may retain product residues. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not inhale exhaust fumes, vapors, sprays or aerosols.
Advice on protection against fire and explosion: Keep away from sources of ignition --- No smoking. Take precautionary measures against static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Vapours are heavier than air and may spread along floors.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Protect from the action of light. Keep only in the original container at a temperature not exceeding 30 °C. Can polymerize with intense heat release. Store locked up.
7.3. Specific end use(s)
no
Safe handling advice: Provide sufficient ventilation and exhaust at the workplace. Provide good room ventilation even at ground level (vapours are heavier than air). Keep container tightly closed. No eating, drinking, smoking, or snuffing tobacco at work. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Wash thoroughly after handling. Follow all SDS/label precautions even after container is emptied because it may retain product residues. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not inhale exhaust fumes, vapors, sprays or aerosols.
Advice on protection against fire and explosion: Keep away from sources of ignition --- No smoking. Take precautionary measures against static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Vapours are heavier than air and may spread along floors.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Protect from the action of light. Keep only in the original container at a temperature not exceeding 30 °C. Can polymerize with intense heat release. Store locked up.
7.3. Specific end use(s)
no
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
8.1. Control parameters
see section 8.2.
8.2. Exposure controls
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health
DNEL
Critical component Routes of exposure Workers Industry / trade Note
glyceroldimethacrylate Inhalation 7.35 mg/m3 Long-term - systemic effects
glyceroldimethacrylate dermal 4.17 mg/kg bodyweight/day Long-term - systemic effects
PNEC
Critical component Routes of exposure Workers Industry / trade Note
glyceroldimethacrylate Freshwater 0.043 mg/l
glyceroldimethacrylate Marine water 0.0043 mg/l
glyceroldimethacrylate Fresh water sediment 0.199 mg/kg (dry weight)
glyceroldimethacrylate Marine sediment 0.0199 mg/kg (dry weight)
glyceroldimethacrylate Soil 0.0144 mg/kg (dry weight)
glyceroldimethacrylate sewage treatment plant (STP) 10 mg/l
Protective measures: Do not breathe in vapours or aerosols. Absolutely avoid contact with the eyes and/or skin. All precautionary measures indicated have to be observed. Avoid exposure - Obtain special instructions before use.
Hygiene measures: Take off all contaminated clothing immediately. Store work clothing separately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream. No eating, drinking, smoking, or snuffing tobacco at work.
Respiratory protection:
Breathing apparatus in case of high concentrations
Hand protection:
Glove material: butyl-rubber
Break through time: 60 min
Glove thickness: 0.7 mm
EN 374
As the product is a mixture of several substances, the durability of the glove materials cannot be calculated in advance and has to be tested before use.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection: tightly fitting goggles
Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear suitable protective clothing and eye/face protection. Take off all contaminated clothing immediately. Safety showers and eye showers should be easily accessible.
see section 8.2.
8.2. Exposure controls
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health
DNEL
Critical component Routes of exposure Workers Industry / trade Note
glyceroldimethacrylate Inhalation 7.35 mg/m3 Long-term - systemic effects
glyceroldimethacrylate dermal 4.17 mg/kg bodyweight/day Long-term - systemic effects
PNEC
Critical component Routes of exposure Workers Industry / trade Note
glyceroldimethacrylate Freshwater 0.043 mg/l
glyceroldimethacrylate Marine water 0.0043 mg/l
glyceroldimethacrylate Fresh water sediment 0.199 mg/kg (dry weight)
glyceroldimethacrylate Marine sediment 0.0199 mg/kg (dry weight)
glyceroldimethacrylate Soil 0.0144 mg/kg (dry weight)
glyceroldimethacrylate sewage treatment plant (STP) 10 mg/l
Protective measures: Do not breathe in vapours or aerosols. Absolutely avoid contact with the eyes and/or skin. All precautionary measures indicated have to be observed. Avoid exposure - Obtain special instructions before use.
Hygiene measures: Take off all contaminated clothing immediately. Store work clothing separately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream. No eating, drinking, smoking, or snuffing tobacco at work.
Respiratory protection:
Breathing apparatus in case of high concentrations
Hand protection:
Glove material: butyl-rubber
Break through time: 60 min
Glove thickness: 0.7 mm
EN 374
As the product is a mixture of several substances, the durability of the glove materials cannot be calculated in advance and has to be tested before use.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection: tightly fitting goggles
Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear suitable protective clothing and eye/face protection. Take off all contaminated clothing immediately. Safety showers and eye showers should be easily accessible.
Stability and reactivity
10.1. Reactivity
see section 10.2.
10.2. Chemical stability
No decomposition if used as directed.
10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.
10.4. Conditions to avoid
Avoid high temperatures and sources of ignition.Protect from the action of light.
The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.
10.5. Incompatible materials
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents.
Free radical initiators.
10.6. Hazardous decomposition products
None when used as directed.
see section 10.2.
10.2. Chemical stability
No decomposition if used as directed.
10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.
10.4. Conditions to avoid
Avoid high temperatures and sources of ignition.Protect from the action of light.
The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.
10.5. Incompatible materials
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents.
Free radical initiators.
10.6. Hazardous decomposition products
None when used as directed.
Disposal considerations
13.1. Waste treatment methods
Product :
Waste is hazardous. It must be disposed of in accordance with the regulations after
consultation of the competent local authorities and the disposal company in a
suitable and licensed facility.
Contaminated packaging :
Contaminated packaging should ideally be emptied; it can then be recycled after
having been decontaminated.
Packaging that cannot be cleaned should be disposed of professionally.
Uncontaminated packaging may be taken for recycling.
Code of waste EWC :
07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics,
synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of
manufacturing, formulation or use in your facilities.
Product :
Waste is hazardous. It must be disposed of in accordance with the regulations after
consultation of the competent local authorities and the disposal company in a
suitable and licensed facility.
Contaminated packaging :
Contaminated packaging should ideally be emptied; it can then be recycled after
having been decontaminated.
Packaging that cannot be cleaned should be disposed of professionally.
Uncontaminated packaging may be taken for recycling.
Code of waste EWC :
07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics,
synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of
manufacturing, formulation or use in your facilities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
