Registration Dossier
Registration Dossier
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EC number: 453-830-4 | CAS number: -
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Emergency measure - Inhalation: Remove to fresh air. If not breathing, administer artificial
respiration with a manual resuscitator only. If breathing
is feeble, administer oxygen. Obtain medical attention
immediately.
Emergency measure - Eyes: Do not delay. Separate eyelids with fingers and immediately
flush eyes with copious quantities of water for at least 15
minutes.
Emergency measure - Skin: Remove contaminated clothing. Wash skin off with plenty of
water. Obtain medical attention if any symptoms develop.
Emergency measure - Ingestion: Wash out mouth with water. Obtain medical attention
urgently. If there is difficulty in breathing, give oxygen.
If breathing fails or stops, give artificial respiration
with a manual resuscitator only.
respiration with a manual resuscitator only. If breathing
is feeble, administer oxygen. Obtain medical attention
immediately.
Emergency measure - Eyes: Do not delay. Separate eyelids with fingers and immediately
flush eyes with copious quantities of water for at least 15
minutes.
Emergency measure - Skin: Remove contaminated clothing. Wash skin off with plenty of
water. Obtain medical attention if any symptoms develop.
Emergency measure - Ingestion: Wash out mouth with water. Obtain medical attention
urgently. If there is difficulty in breathing, give oxygen.
If breathing fails or stops, give artificial respiration
with a manual resuscitator only.
Fire-fighting measures
Recommended extinguishing agent: Use water spray, dry chemical powder, carbon dioxide or
alcohol resistant foam as appropiate. Do not use water jet
Product arising from burning: COx, HCl gas, chloroformate (phosgene)
Product determined by test: N
Protective equipment: Wear full protective clothing and self-contained breathing
apparatus.
alcohol resistant foam as appropiate. Do not use water jet
Product arising from burning: COx, HCl gas, chloroformate (phosgene)
Product determined by test: N
Protective equipment: Wear full protective clothing and self-contained breathing
apparatus.
Accidental release measures
Emergency measures in case of spillage: Evacuate area. Wear self-contained breathing apparatus,
protective clothing, rubber boots and heavy rubber gloves.
Spillages should be absorbed using suitable absorption
medium, such as sand, and be swept up. The sweepings should
be stored in closed containers for disposal. Ventilate area
and wash spill site after material pick up.
protective clothing, rubber boots and heavy rubber gloves.
Spillages should be absorbed using suitable absorption
medium, such as sand, and be swept up. The sweepings should
be stored in closed containers for disposal. Ventilate area
and wash spill site after material pick up.
Handling and storage
Handling: The substance is stored, handled and used in conditions of
good industrial hygiene and in conformity with any local
regulations in order to avoid exposure to skin, eyes and by
inhalation.
Engineering controls in the form of closed system charging
under nitrogen and local exhaust ventilation are provided
at the reactor. When engineering controls are not sufficient
to control exposure, approved respirator protection should
be worn to EN-136 (full face respirator). For manufacturing
areas, skin protection should be provided in the form of
overalls, or full air suits (EN 368) along with impermeable
gloves (EN 374). Rubber, neoprene or other gloves (EN 374)
may be required if solvents, corrosives or other chemicals
are present. Chemical safety goggles (EN 166) should be worn
if a full-face respirator is not worn.
Substance may develop pressure in containers; therefore vent
periodically and open carefully using safety shield.
Caution - substance is corrosive.
Storage: Store in tightly closed fibreboard drums in a dry, dark, and
well ventilated place. Storage at ambient conditions is
acceptable. Maximum temperature for storage should not go
beyond 70°C. Keep away from moisture, bases, alcohols,
amines, and light.
Substance may develop pressure in containers; therefore vent
periodically and open carefully using safety shield.
Store under nitrogen.
Packaging of the substance and or preparation: UN-approved drums suitable for transport of dangerous
substances according to UN transport code UN 3277,class 6.1,
PG II.
good industrial hygiene and in conformity with any local
regulations in order to avoid exposure to skin, eyes and by
inhalation.
Engineering controls in the form of closed system charging
under nitrogen and local exhaust ventilation are provided
at the reactor. When engineering controls are not sufficient
to control exposure, approved respirator protection should
be worn to EN-136 (full face respirator). For manufacturing
areas, skin protection should be provided in the form of
overalls, or full air suits (EN 368) along with impermeable
gloves (EN 374). Rubber, neoprene or other gloves (EN 374)
may be required if solvents, corrosives or other chemicals
are present. Chemical safety goggles (EN 166) should be worn
if a full-face respirator is not worn.
Substance may develop pressure in containers; therefore vent
periodically and open carefully using safety shield.
Caution - substance is corrosive.
Storage: Store in tightly closed fibreboard drums in a dry, dark, and
well ventilated place. Storage at ambient conditions is
acceptable. Maximum temperature for storage should not go
beyond 70°C. Keep away from moisture, bases, alcohols,
amines, and light.
Substance may develop pressure in containers; therefore vent
periodically and open carefully using safety shield.
Store under nitrogen.
Packaging of the substance and or preparation: UN-approved drums suitable for transport of dangerous
substances according to UN transport code UN 3277,class 6.1,
PG II.
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Transport code: UN 3277, II
Transport: Class 6.1 (chloroformates, toxic, corrosive, n.o.s.)
Subsidiary Hazard Class 8
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Stability and reactivity
Danger other than fire: Not known.
Chemical reaction with water: May decompose on exposure to water.
Dust explosion: Not expected - substance is liquid.
Dust explosion determined by test: N
Chemical reaction with water: May decompose on exposure to water.
Dust explosion: Not expected - substance is liquid.
Dust explosion determined by test: N
Disposal considerations
Industry - Possibility of recovery/recycling: Discharge to the environment will be minimal. Recovery from
minor spillages or accidental discharge is not economically
or technically feasible, and waste material will be disposed
of off-site by closed cycle incineration. Recovery of
larger spillages of uncontaminated material for subsequent
use is recommended. As material is used in the process, no
recycling of material is possible.
Industry - Possibility of neutralisation: Not possible.
Industry - Possibility of destruction: controlled discharge: Contaminated containers or spillages of solutions mixed with
inert material (eg. sand or soil) may be disposed of by
incineration in accordance with local regulations.
Industry - Possibility of destruction - incineration: Code 665: Closed cycle incineration is recommended.
Industry - Possibility of destruction - water purification: The substance should not be normally discharged directly to
the sewage system or the aqueous environment. However,
adverse effects on sewage treatment systems would be
unlikely.
Industry - Possibility of destruction - other: None.
Public at large - Possibility of recovery/recycling: Not applicable.
Public at large - Possibility of neutralisation: Not applicable.
Public at large - Possibility of destruction: controlled discharge: Not applicable.
Public at large - Possibility of destruction - incineration: Not applicable.
Public at large - Possibility of destruction - water purification: Not applicable.
Public at large - Possibility of destruction - others: Not applicable.
minor spillages or accidental discharge is not economically
or technically feasible, and waste material will be disposed
of off-site by closed cycle incineration. Recovery of
larger spillages of uncontaminated material for subsequent
use is recommended. As material is used in the process, no
recycling of material is possible.
Industry - Possibility of neutralisation: Not possible.
Industry - Possibility of destruction: controlled discharge: Contaminated containers or spillages of solutions mixed with
inert material (eg. sand or soil) may be disposed of by
incineration in accordance with local regulations.
Industry - Possibility of destruction - incineration: Code 665: Closed cycle incineration is recommended.
Industry - Possibility of destruction - water purification: The substance should not be normally discharged directly to
the sewage system or the aqueous environment. However,
adverse effects on sewage treatment systems would be
unlikely.
Industry - Possibility of destruction - other: None.
Public at large - Possibility of recovery/recycling: Not applicable.
Public at large - Possibility of neutralisation: Not applicable.
Public at large - Possibility of destruction: controlled discharge: Not applicable.
Public at large - Possibility of destruction - incineration: Not applicable.
Public at large - Possibility of destruction - water purification: Not applicable.
Public at large - Possibility of destruction - others: Not applicable.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
