Registration Dossier
Registration Dossier
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EC number: 229-319-5 | CAS number: 6471-78-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures.
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get
medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.
Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances, see toxicological information.
Indication of any immediate medical attention and special treatment needed.
Information not available.
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get
medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.
Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances, see toxicological information.
Indication of any immediate medical attention and special treatment needed.
Information not available.
Fire-fighting measures
Extinguishing media.
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.
Special hazards arising from the substance or mixture.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products. The product is combustible and, when the powder is released into the air in sufficient concentrations and
in the presence of a source of ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage of the solid product
from the container, when it reaches high temperatures or through contact with sources of ignition.
Advice for firefighters.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health.
Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated
water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.
Special hazards arising from the substance or mixture.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products. The product is combustible and, when the powder is released into the air in sufficient concentrations and
in the presence of a source of ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage of the solid product
from the container, when it reaches high temperatures or through contact with sources of ignition.
Advice for firefighters.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health.
Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated
water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
Accidental release measures
Personal precautions, protective equipment and emergency procedures.
If there are no contraindications, spray powder with water to prevent the formation of dust. Avoid breathing vapours/mists/gases.
Wear suitable protective equipment (including personal protective equipment) to prevent any contamination of skin, eyes and personal clothing.
These indications apply for both processing staff and those involved in emergency procedures
Environmental precautions.
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
Methods and material for containment and cleaning up.
Use spark-proof mechanical equipment to collect the leaked product and place it in containers for recovery or disposal. If there are no contraindications, use jets of water to eliminate product residues.
Make sure the leakage site is well aired. Check incompatibility for container material in handling and storage. Contaminated material should be disposed of in compliance with the provisions set forth in section 'disposal considerations'.
If there are no contraindications, spray powder with water to prevent the formation of dust. Avoid breathing vapours/mists/gases.
Wear suitable protective equipment (including personal protective equipment) to prevent any contamination of skin, eyes and personal clothing.
These indications apply for both processing staff and those involved in emergency procedures
Environmental precautions.
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
Methods and material for containment and cleaning up.
Use spark-proof mechanical equipment to collect the leaked product and place it in containers for recovery or disposal. If there are no contraindications, use jets of water to eliminate product residues.
Make sure the leakage site is well aired. Check incompatibility for container material in handling and storage. Contaminated material should be disposed of in compliance with the provisions set forth in section 'disposal considerations'.
Handling and storage
Precautions for safe handling.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment.
Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.
Conditions for safe storage, including any incompatibilities.
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away
from any incompatible materials, see section 'stability and reactivity' for details.
Specific end use(s).
Information not available.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment.
Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.
Conditions for safe storage, including any incompatibilities.
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away
from any incompatible materials, see section 'stability and reactivity' for details.
Specific end use(s).
Information not available.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters.
During the risk assessment process, it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate
otherwise classified (PNOC respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type
filter, whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment.
Exposure controls.
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards.
Provide an emergency shower with face and eye wash station.
HAND PROTECTION
In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374).
Work glove material must be chosen according to the use process and the products that may form.
Latex gloves may cause sensitivity reactions.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body
with soap and water after removing protective clothing.
EYE PROTECTION
Wear a hood visor or protective visor combined with airtight goggles (see standard EN 166).
RESPIRATORY PROTECTION
Use a type P filtering facemask (see standard EN 149) or equivalent device, whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment.
ENVIRONMENTAL EXPOSURE CONTROLS.
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.
During the risk assessment process, it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate
otherwise classified (PNOC respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type
filter, whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment.
Exposure controls.
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards.
Provide an emergency shower with face and eye wash station.
HAND PROTECTION
In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374).
Work glove material must be chosen according to the use process and the products that may form.
Latex gloves may cause sensitivity reactions.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body
with soap and water after removing protective clothing.
EYE PROTECTION
Wear a hood visor or protective visor combined with airtight goggles (see standard EN 166).
RESPIRATORY PROTECTION
Use a type P filtering facemask (see standard EN 149) or equivalent device, whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment.
ENVIRONMENTAL EXPOSURE CONTROLS.
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.
Stability and reactivity
Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.
Chemical stability.
The product is stable in normal conditions of use and storage.
Possibility of hazardous reactions.
No hazardous reactions are foreseeable in normal conditions of use and storage.
Conditions to avoid.
None in particular. However the usual precautions used for chemical products should be respected.
Incompatible materials.
Information not available.
Hazardous decomposition products.
Information not available.
There are no particular risks of reaction with other substances in normal conditions of use.
Chemical stability.
The product is stable in normal conditions of use and storage.
Possibility of hazardous reactions.
No hazardous reactions are foreseeable in normal conditions of use and storage.
Conditions to avoid.
None in particular. However the usual precautions used for chemical products should be respected.
Incompatible materials.
Information not available.
Hazardous decomposition products.
Information not available.
Disposal considerations
Waste treatment methods.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
