Registration Dossier
Registration Dossier
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EC number: 203-653-1 | CAS number: 109-17-1
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General advice: Show this safety data sheet to the doctor in attendance.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed. If symptoms persist, call a physician.
Skin contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. In the case of skin irritation or allergic reactions see a physician.
Eye contact: Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Seek advice of an ophthalmologist if necessary.
Ingestion: Do NOT induce vomiting. Rinse mouth. Consult a physician if necessary.
Protection of first-aiders: Protective suit. In case of insufficient ventilation, wear suitable respiratory equipment.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed. If symptoms persist, call a physician.
Skin contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. In the case of skin irritation or allergic reactions see a physician.
Eye contact: Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Seek advice of an ophthalmologist if necessary.
Ingestion: Do NOT induce vomiting. Rinse mouth. Consult a physician if necessary.
Protection of first-aiders: Protective suit. In case of insufficient ventilation, wear suitable respiratory equipment.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Carbon dioxide (CO2), foam, Dry chemical
Unsuitable extinguishing media: High volume water jet
Special hazards arising from the substance or mixture:
Formation of toxic products through combustion:Carbon oxides
Advice for firefighters:
Specific methods:
In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Do not allow run-off from fire fighting to enter drains or water courses.
Special protective actions for fire-fighters:
In the event of fire, wear self-contained breathing apparatus and protective suit.
Suitable extinguishing media: Carbon dioxide (CO2), foam, Dry chemical
Unsuitable extinguishing media: High volume water jet
Special hazards arising from the substance or mixture:
Formation of toxic products through combustion:Carbon oxides
Advice for firefighters:
Specific methods:
In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Do not allow run-off from fire fighting to enter drains or water courses.
Special protective actions for fire-fighters:
In the event of fire, wear self-contained breathing apparatus and protective suit.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. Prohibit contact with skin and eyes. Avoid inhalation of vapour or mist.
Environmental precautions:
Do not flush into surface water or sanitary sewer system. Do not release into the environment.
Methods and materials for containment and cleaning up:
Recovery: Shovel into suitable container for disposal. Absorb the remainder with an inert absorbent material (sand, vermiculite, perlite). Use clean non-sparking tools to collect absorbed material.
Elimination:
Waste treatment:
Disposal of product: Do not release into the environment. Dispose of in accordance with local regulations.
Disposal of packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal.
Reference to other sections: None.
Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. Prohibit contact with skin and eyes. Avoid inhalation of vapour or mist.
Environmental precautions:
Do not flush into surface water or sanitary sewer system. Do not release into the environment.
Methods and materials for containment and cleaning up:
Recovery: Shovel into suitable container for disposal. Absorb the remainder with an inert absorbent material (sand, vermiculite, perlite). Use clean non-sparking tools to collect absorbed material.
Elimination:
Waste treatment:
Disposal of product: Do not release into the environment. Dispose of in accordance with local regulations.
Disposal of packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal.
Reference to other sections: None.
Handling and storage
Precautions for safe handling:
Technical measures/Precautions:
Storage and handling precautions applicable to products: Liquid. Sensitizing. Provide appropriate exhaust ventilation at machinery. Provide showers and eye-baths.
Safe handling advice:
Remove all sources of ignition. Avoid static electricity build up with connection to earth. In case of insufficient ventilation, wear suitable respiratory equipment.
Hygiene measures:
Take off immediately all contaminated clothing. Prohibit contact with skin and eyes. Wash hands before breaks and at the end of workday. When using do not eat, drink or smoke. Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities:
Keep tightly closed in a dry, cool and well-ventilated place. Store in original container. Protect from frost, heat and sunlight. Keep away from open flames, hot surfaces and sources of ignition. Make sure of the presence of air and inhibitor in the drums. In addition, the product's inhibitor(s) require the presence of dissolved oxygen. An air space is required above the liquid in all containers; avoid storage under an oxygen-free atmosphere.
Storage period: 6 Months, Storage temperature: < 38 °C
Incompatible products: Acids,Bases,Oxidizing agents, Reducing agents.
Packaging material:
Recommended: Baked phenolic lined carbon steel drums, Plastic drum.
To be avoided: copper, Iron.
Technical measures/Precautions:
Storage and handling precautions applicable to products: Liquid. Sensitizing. Provide appropriate exhaust ventilation at machinery. Provide showers and eye-baths.
Safe handling advice:
Remove all sources of ignition. Avoid static electricity build up with connection to earth. In case of insufficient ventilation, wear suitable respiratory equipment.
Hygiene measures:
Take off immediately all contaminated clothing. Prohibit contact with skin and eyes. Wash hands before breaks and at the end of workday. When using do not eat, drink or smoke. Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities:
Keep tightly closed in a dry, cool and well-ventilated place. Store in original container. Protect from frost, heat and sunlight. Keep away from open flames, hot surfaces and sources of ignition. Make sure of the presence of air and inhibitor in the drums. In addition, the product's inhibitor(s) require the presence of dissolved oxygen. An air space is required above the liquid in all containers; avoid storage under an oxygen-free atmosphere.
Storage period: 6 Months, Storage temperature: < 38 °C
Incompatible products: Acids,Bases,Oxidizing agents, Reducing agents.
Packaging material:
Recommended: Baked phenolic lined carbon steel drums, Plastic drum.
To be avoided: copper, Iron.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls:
Appropriate engineering controls: When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment.
Personal protective equipment:
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment.
Hand protection: Gloves nitrile rubber
Products used with solvents:
Do not use: Natural Rubber, Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye/face protection: Safety glasses with side-shields, Do not wear contact lenses.
Skin and body protection: Long sleeved clothing
Environmental exposure controls:
Environmental precautions: Do not flush into surface water or sanitary sewer system. Do not release into the environment.
Appropriate engineering controls: When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment.
Personal protective equipment:
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment.
Hand protection: Gloves nitrile rubber
Products used with solvents:
Do not use: Natural Rubber, Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye/face protection: Safety glasses with side-shields, Do not wear contact lenses.
Skin and body protection: Long sleeved clothing
Environmental exposure controls:
Environmental precautions: Do not flush into surface water or sanitary sewer system. Do not release into the environment.
Stability and reactivity
Chemical stability:
The product is stable under recommended handling and storage conditions.
Possibility of hazardous reactions:
Inhibitors have been added to stabilize this product. Maintaining air in the storage containers is important to keep inhibitors active. Unless inhibited, hazardous polymerisation may occur. Polymerization is exothermic and can degenerate into an uncontrolled reaction.
Conditions to avoid:
Heat, flames and sparks. Remove all sources of ignition. Take precautionary measures against static discharges.
Incompatible materials to avoid: Acids, Bases, Oxidizing agents, Reducing agents.
Hazardous decomposition products:
Formation of toxic products through combustion: Carbon oxides.
The product is stable under recommended handling and storage conditions.
Possibility of hazardous reactions:
Inhibitors have been added to stabilize this product. Maintaining air in the storage containers is important to keep inhibitors active. Unless inhibited, hazardous polymerisation may occur. Polymerization is exothermic and can degenerate into an uncontrolled reaction.
Conditions to avoid:
Heat, flames and sparks. Remove all sources of ignition. Take precautionary measures against static discharges.
Incompatible materials to avoid: Acids, Bases, Oxidizing agents, Reducing agents.
Hazardous decomposition products:
Formation of toxic products through combustion: Carbon oxides.
Disposal considerations
Waste treatment:
Disposal of product:
Do not release into the environment. Dispose of in accordance with local regulations.
Disposal of packaging:
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Disposal of product:
Do not release into the environment. Dispose of in accordance with local regulations.
Disposal of packaging:
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
