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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
disregarded due to major methodological deficiencies
Study period:
1990
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
other: Composition of "n-hexyl lithium concentrate" is not indicated in the report.
Cross-referenceopen allclose all
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to other study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1990
Report date:
1990

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
Directive 84/449/EWG
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: DIN 51 794 (January 1978)
Deviations:
no
Principles of method if other than guideline:
NA

Test material

Constituent 1
Chemical structure
Reference substance name:
N-hexyllithium
EC Number:
404-950-0
EC Name:
N-hexyllithium
Cas Number:
21369-64-2
Molecular formula:
n-C6H13Li
IUPAC Name:
lithium(1+) hexan-1-ide
Details on test material:
NA

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
ca. 120 °C
Remarks on result:
other:

Any other information on results incl. tables

Below the ignition temperature, the sparks were already observed at 42 °C.

Applicant's summary and conclusion

Conclusions:
The auto-flammability was determined at 120 °C.
Executive summary:

The auto-flammability was determined at 120 °C.