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Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
October 15 - October 16, 2019
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: OECD 113
Deviations:
no
GLP compliance:
no
Key result
Parameter:
other: Energy release in J/g
Value:
207

Thermal stability

Two DSC measurements in closed glass crucibles showed two endothermal effects in the temperature range of 75 - 95 °C and 120 - 135 °C. An exothermal effect was observed in the temperature range of 435 - 470 °C with a maximum energy release of 207 J/g.

 

Ident-No.

Weigth/mg

Final temperature / °C

Temperature range / °C

Type of effect

Energy / J/g

38865

11.73

500

75 - 95

120 - 135

440 - 470

Endothermal

Endothermal

Exothermal

n.r.

n.r.

185

38870

11.37

500

75 - 95

120 - 135

435 - 460

Endothermal

Endothermal

Exothermal

n.r.

n.r.

207

 

Explosive properties

The heat of decomposition in the DCS measurements was below 500 J/g.Therefore, the main test on explosive properties was not necessary.

Interpretation of results:
GHS criteria not met
Conclusions:
The test item is not an explosive.
Executive summary:

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A. 14.

Description of key information

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A. 14.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification

Classification, Labelling, and Packaging Regulation (EC) No 1272/2008

Based on the result, the substance is not considered to be classified for explosiveness.