Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Endpoint summary

Administrative data

Description of key information

VCl3 is very hygroscopic and gives, in contact of humidity :

VCl3 + H2O => VOCl + 2 HCL

VOCl + 1/2Cl2 => VOCl2

The dissolution reaction in water is instantaneous (half-life of VCl3 < 1 hour – VCl3 can be considered as a hydrolytically unstable substance), gives white fumes of HCl and the pH of the solution is < 2.

This reaction is verified weekly in a laboratory by the color change when VCl3 is exposed to the air (red to green).

Testing for hydrolysis is then technically impossible and scientifically unjustified: instantaneous decomposition of VCl4 in presence of humidity of air do not allow hydrolysis testing.

Additional information