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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Remove contaminated clothing.

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:

Wash thoroughly with soap and water

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Most important symptoms and effects, both acute and delayed

Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11., Further symptoms are possible

Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:

water spray, dry powder, alcohol-resistant foam, carbon dioxide

Special hazards arising from the substance or mixture

Endangering substances: nitrogen oxides, carbon oxides

Advice: The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.

Advice for fire-fighters

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:

Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Avoid inhalation. Avoid contact with the skin, eyes and clothing.

Environmental precautions

Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up

For large amounts: Pump off product.

For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

Handling and storage

Precautions for safe handling

Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion:

The product is combustible. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Temperature class: T3 (Autoignition temperature >200 °C).

Conditions for safe storage, including any incompatibilities

Segregate from acids and acid forming substances.

Suitable materials for containers: Carbon steel (Iron), Stainless steel 1.4401, Stainless steel 1.4301 (V2), High density polyethylene (HDPE), glass, Low density polyethylene (LDPE)

Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage class according to TRGS 510 (originally VCI, Germany): (10) Combustible liquids

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Control parameters

Components with occupational exposure limits

No substance specific occupational exposure limits known.

PNEC

freshwater: 0,1 mg/l

marine water: 0,0045 mg/l

intermittent release: 1 mg/l

sediment (freshwater): 0,78 mg/kg

sediment (marine water): 0,0351 mg/kg

soil: 0,097 mg/kg

STP: 10 mg/l

oral (secondary poisoning):

No PNEC oral derived, as accumulation in organisms is not to be expected.

DNEL

worker:

Long-term exposure- systemic effects, Inhalation: 7,9 mg/m3

worker:

Long-term exposure- systemic effects, dermal: 5,6 mg/kg

consumer:

Long-term exposure- systemic effects, Inhalation: 0,4 mg/m3

consumer:

Long-term exposure- systemic effects, dermal: 0,67 mg/kg

consumer:

Long-term exposure- systemic effects, oral: 0,13 mg/kg

Exposure controls

Personal protective equipment

Respiratory protection:

Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A) Consider the risk management measures as outlined in the exposure scenario.

Hand protection:

Chemical resistant protective gloves (EN ISO 374-1)

Performance level 6, corresponding to a breakthrough time of >480 min according to EN ISO 374-1

butyl rubber (butyl) - 0.7 mm coating thickness

nitrile rubber (NBR) - 0.4 mm coating thickness

fluoroelastomer (FKM) - 0.7 mm coating thickness

Manufacturer's directions for use should be observed because of great diversity of types.

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:

Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Take off immediately all contaminated clothing. Store work clothing separately.

Stability and reactivity

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:

No corrosive effect on metal.

Formation of flammable gases:       Remarks:       Forms no flammable gases in the presence of water.

Chemical stability

The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions

The progress of reaction is exothermic. Reacts with halogenated compounds. Reacts with oxidizing agents. Reacts with acids. Reacts with acid chlorides. Incompatible with acid chlorides and acid anhydrides.

Conditions to avoid

Avoid extreme temperatures. See SDS section 7 - Handling and storage.

Incompatible materials

Substances to avoid:

acid chlorides, acid anhydrides, acid forming substances, acids, oxidizing agents, nitrosating agents

Hazardous decomposition products

Hazardous decomposition products:

carbon oxides, nitrogen oxides, nitrous gases

Disposal considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.

The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.

Contaminated packaging:

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.