Notified classification and labelling according to CLP criteria
EC / List no.
|
Name |
CAS Number
|
Additional Notified Information
|
|---|---|---|---|
| 247-714-0 | Methylenediphenyl diisocyanate | 26447-40-5 |
State/Form
|
| Classification | Labelling | Specific Concentration limits, M-Factors | Notes |
Classification affected by Impurities / Additives
|
||
|---|---|---|---|---|---|---|
| Hazard Class and Category Code(s) | Hazard Statement Code(s) | Hazard Statement Code(s) | Supplementary Hazard Statement Code(s) | |||
| Skin Irrit. 2 | H315 | H315 |
Note 2
Note C |
|||
| Skin Sens. 1 | H317 | H317 | ||||
| Eye Irrit. 2 | H319 | H319 | ||||
| Acute Tox. 4 | H332 | H332 | ||||
| Resp. Sens. 1 | H334 | H334 | ||||
| STOT SE 2 | H335 (not determined) | H335 | ||||
| Carc. 2 | H351 (dermal,inhalati...) | H351 | ||||
| STOT RE 2 | H373 (not determined) | H373 | ||||
| Signal Words | Pictograms | ||||||
|---|---|---|---|---|---|---|---|
| Warning |
|
Classification
| Physical and Chemical hazards | |||
|---|---|---|---|
| Hazard Category | Hazard Statement |
Reason for no Classification
|
|
| Explosives | data conclusive but not sufficient for classification | ||
| Flammable Gases and Chemically Unstable Gases | data conclusive but not sufficient for classification | ||
| Flammable Aerosols | data conclusive but not sufficient for classification | ||
| Oxidising Gases | data conclusive but not sufficient for classification | ||
| Gases Under Pressure | data conclusive but not sufficient for classification | ||
| Flammable Liquids | data conclusive but not sufficient for classification | ||
| Flammable Solids | data conclusive but not sufficient for classification | ||
| Self-reactive Substances and Mixtures | data conclusive but not sufficient for classification | ||
| Pyrophoric Liquids | data conclusive but not sufficient for classification | ||
| Pyrophoric Solids | data conclusive but not sufficient for classification | ||
| Self-heating Substances and Mixtures | data conclusive but not sufficient for classification | ||
| Substances and Mixtures which in contact with water emit flammable gases | data conclusive but not sufficient for classification | ||
| Oxidising Liquids | data conclusive but not sufficient for classification | ||
| Oxidising Solids | data conclusive but not sufficient for classification | ||
| Organic Peroxides | data conclusive but not sufficient for classification | ||
| Substances and Mixtures corrosive to Metals | data conclusive but not sufficient for classification | ||
| Desensitized Explosives | Data lacking | ||
| Human Health hazards | |||
| Hazard Category | Hazard Statement |
Reason for no Classification
|
|
| Acute Toxicity - Oral | data conclusive but not sufficient for classification | ||
| Acute Toxicity - Dermal | data conclusive but not sufficient for classification | ||
| Acute Toxicity - Inhalation | Acute Tox. 4 | H332 | |
| Skin Corrosion / Irritation | Skin Irrit. 2 | H315 | |
| Serious Eye Damage / Eye Irritation | Eye Irrit. 2 | H319 | |
| Respiratory Sensitisation | Resp. Sens. 1 | H334 | |
| Skin Sensitisation | Skin Sens. 1 | H317 | |
| Aspiration Hazard | data conclusive but not sufficient for classification | ||
| Germ Cell Mutagenicity | Hazard Category | Hazard Statement |
Reason for no Classification
|
| Germ Cell Mutagenicity | data conclusive but not sufficient for classification | ||
| Carcinogenicity | Hazard Category | Hazard Statement |
Reason for no Classification
|
| Carcinogenicity | Carc. 2 | H351 | |
| Route of exposure | dermal,inhalation | ||
| Reproductive Toxicity | Hazard Category | Hazard Statement |
Reason for no Classification
|
| Reproductive Toxicity | data conclusive but not sufficient for classification | ||
| Effects on or via Lactation | data conclusive but not sufficient for classification | ||
| Specific target organ toxicity - Single | Hazard Category | Hazard Statement |
Reason for no Classification
|
| Specific target organ toxicity - Single | STOT SE 2 | H335 | |
| Affected Organs | not determined | ||
| Specific target organ toxicity - Repeated | Hazard Category | Hazard Statement |
Reason for no Classification
|
| Specific target organ toxicity - Repeated | STOT RE 2 | H373 | |
| Affected Organs | not determined | ||
| Environmental Hazards | |||
| Hazardous to the aquatic environment | Hazard Category | Hazard Statement |
Reason for no Classification
|
| Hazardous to the aquatic environment - acute | data conclusive but not sufficient for classification | ||
| Hazardous to the aquatic environment - chronic | data conclusive but not sufficient for classification | ||
| Hazardous to the atmospheric environment | Hazard Category | Hazard Statement |
Reason for no Classification
|
| Hazardous to the ozone layer | data conclusive but not sufficient for classification | ||
| Additional Hazard Classes | Additional Hazard Statements |
|---|---|
| No available Data | |
Labelling
| Hazard Statement Code(s) | Phrase | Additional Text |
|---|---|---|
| H315 | Causes skin irritation. | |
| H319 | Causes serious eye irritation. | |
| H317 | May cause an allergic skin reaction. | |
| H332 | Harmful if inhaled. | |
| H335 | May cause respiratory irritation. | |
| H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled. | |
| H351 | Suspected of causing cancer |
|
| H373 | May cause damage to organs |
| Note Title | Note Text |
|---|---|
| Note 2 | The concentration of isocyanate stated is the percentage by weight of the free monomer calculated with reference to the total weight of the mixture. |
| Note C | Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers. , In this case the supplier must state on the label whether the substance is a specific isomer or a mixture of isomers. |