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Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse.
Flush thoroughly with water. If irritation occurs, get medical assistance.
Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Inappropriate Extinguishing Media: Straight streams of water
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: Hazardous material.
Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by pumping or with suitable absorbent.
Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity).
Loading/Unloading Temperature: [Ambient]
Transport Temperature: [Ambient]
Transport Pressure: [Ambient]
Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.
The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be earthed and bonded to prevent accumulation of static charge.
Storage Temperature: [Ambient]
Storage Pressure: [Ambient]
Suitable Containers/Packing: Tankers; Railcars; Tank Trucks; Barges; Drums
Suitable Materials and Coatings (Chemical Compatibility): Inorganic Zinc Coatings; Amine Epoxy; Polyamide Epoxy; Epoxy Phenolic; Neoprene; Carbon Steel; Stainless Steel
Unsuitable Materials and Coatings: Vinyl Coatings; Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene monomer (EPDM); Polystyrene
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-proof ventilation equipment.
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Half-face filter respirator European Committee for Standardization (CEN) standards EN 136, 140 and 405 provide respirator masks and EN 149 and 143 provide filter recommendations., Type A filter material
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves. Nitrile, CEN standards EN 420 and EN 374 provide general requirements and lists of glove types.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Open flames and high energy ignition sources.
MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
European Waste Code: 08 XX XX
NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s).
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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