Registration Dossier
Registration Dossier
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EC number: 213-234-5 | CAS number: 931-36-2
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2).
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions).
Fire-fighting measures
Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide.
Special hazards arising from the substance or mixture:
carbon oxides and nitrogen oxides can be released in case of fire.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not empty into drains.
Methods and material for containment and cleaning up
For small amounts: Allow to solidify and sweep/shovel up.
For large amounts: Allow to solidify and sweep/shovel up.
Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in the section "exposure controls/personal protection".
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Protect against moisture.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
PNEC
freshwater: 0.0681 mg/l
marine water: 0.00681 mg/l
intermittent release: 0.681 mg/l
STP: 65 mg/l
sediment (freshwater): 34.9 mg/kg
sediment (marine water): 3.49 mg/kg
soil: 6.91 mg/kg
oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.
DNEL
worker:
Long-term exposure - systemic effects, Inhalation: 2,8 mg/m3
worker:
Long-term exposure - systemic effects, dermal: 1,6 mg/kg
worker:
Long-term exposure - local effects, dermal: 0.289 mg/cm2
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A).
Hand protection:
Chemical resistant protective gloves (EN 374).
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness.
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
natural rubber/natural latex (NR) - 0.5 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
Use additional heat protection gloves when handling hot molten masses (EN 407), e.g. of textile or leather.
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with the skin, eyes and clothing. Avoid inhalation of vapour. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse.
Environmental exposure controls
For information regarding environmental exposure controls, see section "Accidental release measures".
Stability and reactivity
Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals: Not corrosive to steel and aluminium.
Formation of flammable gases: Forms no flammable gases in the presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Reacts with strong acids. Exothermic reaction.
Conditions to avoid
See section "handling and storage".
Incompatible materials
Substances to avoid: strong acids.
Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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